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@ARTICLE{Merso:1025019,
      author       = {Merso, Semaw Kebede and Tekaligne, Teshager Mekonnen and
                      Adigo Weret, Misganaw and Shitaw, Kassie Nigus and
                      Nikodimos, Yosef and Yang, Sheng-Chiang and Muche, Zabish
                      Bilew and Taklu, Bereket Woldegbreal and Hotasi, Boas Tua
                      and Chang, Chia-Yu and Jiang, Shi-Kai and Brunklaus, Gunther
                      and Winter, Martin and Wu, She-Huang and Su, Wei-Nien and
                      Mou, Chung-Yuan and Hwang, Bing Joe},
      title        = {{M}ultiple protective layers for suppressing {L}i dendrite
                      growth and improving the cycle life of anode-free lithium
                      metal batteries},
      journal      = {The chemical engineering journal},
      volume       = {485},
      issn         = {1385-8947},
      address      = {Amsterdam},
      publisher    = {Elsevier},
      reportid     = {FZJ-2024-02613},
      pages        = {149547 -},
      year         = {2024},
      abstract     = {Anode-free lithium metal batteries (AFLMBs) have sparked
                      considerable attention in recent years because of their
                      potential for high energy density; however, they suffer from
                      severe Li dendrite growth and unstable solid electrolyte
                      interphase (SEI), which typically result in rapid capacity
                      decay. Herein, we demonstrate a long-life anode-free pouch
                      cell by designing a dual-coating protective layer
                      (Cu-Sn@SFPH) electrode with Sn-coated Cu (denoted as Cu-Sn)
                      as the bottom layer and SrF2 nanoparticles strengthened by
                      poly (vinylidene fluoride)-co-hexafluoropropylene (PVDF-HFP)
                      as the top layer. The in-situ formed LiF-rich SEI enables
                      fast Li+ transfer, while the lithiophilic Li-Sn and Li-Sr
                      alloy layers serve as nucleation seeds for uniform Li
                      deposition. The dual-coated Cu electrode in the
                      Cu-Sn@SFPH||Li cell exhibits remarkable cycling stability
                      for more than 3,200 h at a capacity of 2 mAh cm−2. The
                      NCM111||Cu-Sn@SFPH pouch cell demonstrates outstanding
                      performance with a capacity retention of 72.1 $\%$ and an
                      average Coulombic efficiency (CE) of 99.9 $\%$ for 120
                      cycles. Under practical conditions, with NCM cathodes and a
                      lean electrolyte volume, this design strategy opens a new
                      approach to AFLMBs.},
      cin          = {IEK-12},
      cid          = {I:(DE-Juel1)IEK-12-20141217},
      pnm          = {1221 - Fundamentals and Materials (POF4-122) / LiBEST2 -
                      Lithium-Batterie-Konzepte mit hoher Energiedichte, Leistung
                      und Sicherheit (13XP0304A)},
      pid          = {G:(DE-HGF)POF4-1221 / G:(BMBF)13XP0304A},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:001202517800001},
      doi          = {10.1016/j.cej.2024.149547},
      url          = {https://juser.fz-juelich.de/record/1025019},
}