001025058 001__ 1025058
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001025058 0247_ $$2doi$$a10.1149/MA2023-02653058mtgabs
001025058 0247_ $$2ISSN$$a1091-8213
001025058 0247_ $$2ISSN$$a2151-2043
001025058 037__ $$aFZJ-2024-02646
001025058 082__ $$a540
001025058 1001_ $$aHesper, Jakob Michael$$b0
001025058 245__ $$aIdentification and Quantification of Lithium Ion Battery Electrolyte Residues in Blackmass Via Headspace-GC-MS/FID
001025058 260__ $$aPennington, NJ$$bSoc.$$c2023
001025058 3367_ $$2DRIVER$$aarticle
001025058 3367_ $$2DataCite$$aOutput Types/Journal article
001025058 3367_ $$0PUB:(DE-HGF)16$$2PUB:(DE-HGF)$$aJournal Article$$bjournal$$mjournal$$s1712835524_20085
001025058 3367_ $$2BibTeX$$aARTICLE
001025058 3367_ $$2ORCID$$aJOURNAL_ARTICLE
001025058 3367_ $$00$$2EndNote$$aJournal Article
001025058 500__ $$aHier handelt es sich lediglich um einen Abstract.
001025058 520__ $$aDue to the increasing demand for lithium-ion batteries (LIBs) in recent years, the demand for resources has also risen. As a result, the amount of LIBs that have reached the end of their life is increasing, leading to stricter guidelines that require certain proportions of recycled materials in the production of new LIBs. Typical recycling strategies start by deactivating, dismantling and shredding LIBs, thereby generating blackmass consisting of active and inactive materials (e.g. Li, Mn, Ni, Co, Cu and organic carbonates). However, black mass is a non-standardized resource, and its composition and purity vary depending on the respective process. 1,2 Therefore, it is essential to characterize and quantify its composition in order to make use of this highly variable resource stream while maintaining quality and safety.This work aims to identify and quantify organic electrolyte residues in black mass without further sample preparation. To achieve this, the samples were agitated using a headspace sampler and then analyzed by gas chromatography-mass spectrometry (GC-MS) and flame ionization detector (FID). Linear and cyclic carbonates such as dimethyl carbonate, ethyl methyl carbonate, and ethylene carbonate, as well as aging products such as 2,5-dioxahexanedioic acid dimethyl ester (DMDOHC), were detected. The identification results were compared to those achieved by thermodesorption and solid-phase microextraction.Overall, this study demonstrates a method for identifying and quantifying organic electrolyte residues in black mass, which can aid in the development of more efficient and sustainable recycling processes for LIBs.References(1) Peschel, C.; van Wickeren, S.; Preibisch, Y.; Naber, V.; Werner, D.; Frankenstein, L.; Horsthemke, F.; Peuker, U.; Winter, M.; Nowak, S. Comprehensive Characterization of Shredded Lithium-Ion Battery Recycling Material. Chemistry (Weinheim an der Bergstrasse, Germany)2022, 28, e202200485.(2) Neumann, J.; Petranikova, M.; Meeus, M.; Gamarra, J. D.; Younesi, R.; Winter, M.; Nowak, S. Recycling of Lithium‐Ion Batteries—Current State of the Art, Circular Economy, and Next Generation Recycling. Advanced Energy Materials2022, 761, 2102917.
001025058 536__ $$0G:(DE-HGF)POF4-1221$$a1221 - Fundamentals and Materials (POF4-122)$$cPOF4-122$$fPOF IV$$x0
001025058 588__ $$aDataset connected to CrossRef, Journals: juser.fz-juelich.de
001025058 7001_ $$0P:(DE-Juel1)166130$$aWinter, Martin$$b1
001025058 7001_ $$0P:(DE-HGF)0$$aNowak, Sascha$$b2
001025058 773__ $$0PERI:(DE-600)2438749-6$$a10.1149/MA2023-02653058mtgabs$$gVol. MA2023-02, no. 65, p. 3058 - 3058$$n65$$p3058 - 3058$$tMeeting abstracts$$vMA2023-02$$x1091-8213$$y2023
001025058 909CO $$ooai:juser.fz-juelich.de:1025058$$pVDB
001025058 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)166130$$aForschungszentrum Jülich$$b1$$kFZJ
001025058 9131_ $$0G:(DE-HGF)POF4-122$$1G:(DE-HGF)POF4-120$$2G:(DE-HGF)POF4-100$$3G:(DE-HGF)POF4$$4G:(DE-HGF)POF$$9G:(DE-HGF)POF4-1221$$aDE-HGF$$bForschungsbereich Energie$$lMaterialien und Technologien für die Energiewende (MTET)$$vElektrochemische Energiespeicherung$$x0
001025058 9141_ $$y2024
001025058 9201_ $$0I:(DE-Juel1)IEK-12-20141217$$kIEK-12$$lHelmholtz-Institut Münster Ionenleiter für Energiespeicher$$x0
001025058 980__ $$ajournal
001025058 980__ $$aVDB
001025058 980__ $$aI:(DE-Juel1)IEK-12-20141217
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001025058 981__ $$aI:(DE-Juel1)IMD-4-20141217