001025145 001__ 1025145
001025145 005__ 20250204113837.0
001025145 0247_ $$2doi$$a10.1002/ange.202315371
001025145 0247_ $$2ISSN$$a0932-2132
001025145 0247_ $$2ISSN$$a0044-8249
001025145 0247_ $$2ISSN$$a0932-2159
001025145 0247_ $$2ISSN$$a0170-9046
001025145 0247_ $$2ISSN$$a0170-9054
001025145 0247_ $$2ISSN$$a0932-2140
001025145 0247_ $$2ISSN$$a1521-3757
001025145 0247_ $$2datacite_doi$$a10.34734/FZJ-2024-02722
001025145 037__ $$aFZJ-2024-02722
001025145 082__ $$a660
001025145 1001_ $$0P:(DE-HGF)0$$aHe, Yueyue$$b0
001025145 245__ $$aEntropy‐Mediated Stable Structural Evolution of Prussian White Cathodes for Long‐Life Na‐Ion Batteries
001025145 260__ $$aWeinheim$$bWiley-VCH$$c2024
001025145 3367_ $$2DRIVER$$aarticle
001025145 3367_ $$2DataCite$$aOutput Types/Journal article
001025145 3367_ $$0PUB:(DE-HGF)16$$2PUB:(DE-HGF)$$aJournal Article$$bjournal$$mjournal$$s1714732237_26324
001025145 3367_ $$2BibTeX$$aARTICLE
001025145 3367_ $$2ORCID$$aJOURNAL_ARTICLE
001025145 3367_ $$00$$2EndNote$$aJournal Article
001025145 520__ $$aThe high-entropy approach is applied to monoclinic Prussian White (PW) Na-ion cathodes to address the issue of unfavorable multilevel phase transitions upon electrochemical cycling, leading to poor stability and capacity decay. A series of Mn-based samples with up to six metal species sharing the N-coordinated positions was synthesized. The material of composition Na1.65Mn0.4Fe0.12Ni0.12Cu0.12Co0.12Cd0.12[Fe(CN)6]0.92□0.08 ⋅ 1.09H2O was found to exhibit superior cyclability over medium/low-entropy and conventional single-metal PWs. We also report, to our knowledge for the first time, that a high-symmetry crystal structure may be advantageous for high-entropy PWs during battery operation. Computational comparisons of the formation enthalpy demonstrate that the compositionally less complex materials are prone to phase transitions, which negatively affect cycling performance. Based on data from complementary characterization techniques, an intrinsic mechanism for the stability improvement of the disordered PW structure upon Na+ insertion/extraction is proposed, namely the dual effect of suppression of phase transitions and mitigation of gas evolution.
001025145 536__ $$0G:(DE-HGF)POF4-1212$$a1212 - Materials and Interfaces (POF4-121)$$cPOF4-121$$fPOF IV$$x0
001025145 588__ $$aDataset connected to CrossRef, Journals: juser.fz-juelich.de
001025145 7001_ $$0P:(DE-HGF)0$$aDreyer, Sören L.$$b1
001025145 7001_ $$0P:(DE-Juel1)188938$$aTing, Yin-Ying$$b2$$ufzj
001025145 7001_ $$0P:(DE-HGF)0$$aMa, Yuan$$b3
001025145 7001_ $$0P:(DE-Juel1)188821$$aHu, Yang$$b4$$ufzj
001025145 7001_ $$0P:(DE-HGF)0$$aGoonetilleke, Damian$$b5
001025145 7001_ $$0P:(DE-HGF)0$$aTang, Yushu$$b6
001025145 7001_ $$0P:(DE-HGF)0$$aDiemant, Thomas$$b7
001025145 7001_ $$0P:(DE-HGF)0$$aZhou, Bei$$b8
001025145 7001_ $$0P:(DE-Juel1)137024$$aKowalski, Piotr M.$$b9$$ufzj
001025145 7001_ $$0P:(DE-HGF)0$$aFichtner, Maximilian$$b10
001025145 7001_ $$0P:(DE-HGF)0$$aHahn, Horst$$b11
001025145 7001_ $$0P:(DE-HGF)0$$aAghassi-Hagmann, Jasmin$$b12
001025145 7001_ $$00000-0002-4336-263X$$aBrezesinski, Torsten$$b13
001025145 7001_ $$00000-0002-1304-3398$$aBreitung, Ben$$b14
001025145 7001_ $$00000-0002-4125-2867$$aMa, Yanjiao$$b15
001025145 773__ $$0PERI:(DE-600)1479266-7$$a10.1002/ange.202315371$$gVol. 136, no. 7, p. e202315371$$n7$$pe202315371$$tAngewandte Chemie$$v136$$x0932-2132$$y2024
001025145 8564_ $$uhttps://juser.fz-juelich.de/record/1025145/files/Angewandte%20Chemie%20-%202023%20-%20He%20-%20Entropy%E2%80%90Mediated%20Stable%20Structural%20Evolution%20of%20Prussian%20White%20Cathodes%20for%20Long%E2%80%90Life.pdf$$yOpenAccess
001025145 8564_ $$uhttps://juser.fz-juelich.de/record/1025145/files/Angewandte%20Chemie%20-%202023%20-%20He%20-%20Entropy%E2%80%90Mediated%20Stable%20Structural%20Evolution%20of%20Prussian%20White%20Cathodes%20for%20Long%E2%80%90Life.gif?subformat=icon$$xicon$$yOpenAccess
001025145 8564_ $$uhttps://juser.fz-juelich.de/record/1025145/files/Angewandte%20Chemie%20-%202023%20-%20He%20-%20Entropy%E2%80%90Mediated%20Stable%20Structural%20Evolution%20of%20Prussian%20White%20Cathodes%20for%20Long%E2%80%90Life.jpg?subformat=icon-1440$$xicon-1440$$yOpenAccess
001025145 8564_ $$uhttps://juser.fz-juelich.de/record/1025145/files/Angewandte%20Chemie%20-%202023%20-%20He%20-%20Entropy%E2%80%90Mediated%20Stable%20Structural%20Evolution%20of%20Prussian%20White%20Cathodes%20for%20Long%E2%80%90Life.jpg?subformat=icon-180$$xicon-180$$yOpenAccess
001025145 8564_ $$uhttps://juser.fz-juelich.de/record/1025145/files/Angewandte%20Chemie%20-%202023%20-%20He%20-%20Entropy%E2%80%90Mediated%20Stable%20Structural%20Evolution%20of%20Prussian%20White%20Cathodes%20for%20Long%E2%80%90Life.jpg?subformat=icon-640$$xicon-640$$yOpenAccess
001025145 909CO $$ooai:juser.fz-juelich.de:1025145$$pdnbdelivery$$pdriver$$pVDB$$popen_access$$popenaire
001025145 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)188938$$aForschungszentrum Jülich$$b2$$kFZJ
001025145 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)188821$$aForschungszentrum Jülich$$b4$$kFZJ
001025145 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)137024$$aForschungszentrum Jülich$$b9$$kFZJ
001025145 9131_ $$0G:(DE-HGF)POF4-121$$1G:(DE-HGF)POF4-120$$2G:(DE-HGF)POF4-100$$3G:(DE-HGF)POF4$$4G:(DE-HGF)POF$$9G:(DE-HGF)POF4-1212$$aDE-HGF$$bForschungsbereich Energie$$lMaterialien und Technologien für die Energiewende (MTET)$$vPhotovoltaik und Windenergie$$x0
001025145 9141_ $$y2024
001025145 915__ $$0LIC:(DE-HGF)CCBY4$$2HGFVOC$$aCreative Commons Attribution CC BY 4.0
001025145 915__ $$0StatID:(DE-HGF)3001$$2StatID$$aDEAL Wiley$$d2023-08-23$$wger
001025145 915__ $$0StatID:(DE-HGF)0510$$2StatID$$aOpenAccess
001025145 915__ $$0StatID:(DE-HGF)0420$$2StatID$$aNationallizenz$$d2024-12-17$$wger
001025145 915__ $$0StatID:(DE-HGF)0200$$2StatID$$aDBCoverage$$bSCOPUS$$d2024-12-17
001025145 915__ $$0StatID:(DE-HGF)0300$$2StatID$$aDBCoverage$$bMedline$$d2024-12-17
001025145 915__ $$0StatID:(DE-HGF)0600$$2StatID$$aDBCoverage$$bEbsco Academic Search$$d2024-12-17
001025145 915__ $$0StatID:(DE-HGF)0030$$2StatID$$aPeer Review$$bASC$$d2024-12-17
001025145 920__ $$lyes
001025145 9201_ $$0I:(DE-Juel1)IEK-13-20190226$$kIEK-13$$lIEK-13$$x0
001025145 9801_ $$aFullTexts
001025145 980__ $$ajournal
001025145 980__ $$aVDB
001025145 980__ $$aUNRESTRICTED
001025145 980__ $$aI:(DE-Juel1)IEK-13-20190226
001025145 981__ $$aI:(DE-Juel1)IET-3-20190226