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| Hauptseite > Publikationsdatenbank > An Analysis of Calendaric Aging over 5 Years of Ni‐rich 18650‐Cells with Si/C Anodes > print |
| Hauptseite > Publikationsdatenbank > An Analysis of Calendaric Aging over 5 Years of Ni‐rich 18650‐Cells with Si/C Anodes > print |
| 001 | 1025197 | ||
| 005 | 20250204113838.0 | ||
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| 100 | 1 | _ | |a Frie, Fabian |0 0000-0001-7022-9140 |b 0 |e Corresponding author |
| 245 | _ | _ | |a An Analysis of Calendaric Aging over 5 Years of Ni‐rich 18650‐Cells with Si/C Anodes |
| 260 | _ | _ | |a Weinheim |c 2024 |b Wiley-VCH |
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| 520 | _ | _ | |a Calendaric lifetime testing of lithium-ion cells is time-consuming and resource-intensive. As Dubarry et al.[1] state, testing is often limited to a few aging conditions. This paper presents the results of a long-term aging study on lithium-ion cells with a nickel-rich NCA cathode and a graphite-silicon anode. 69 cells were stored at 5 different voltages and under 4 different temperatures for 5 years. Regular reference performance tests (RPT) provide insights for State of Health (SoH) calculation and further analysis through differential voltage analysis. The results are verified against post-mortem analyses. The long aging period enables accurate determination of aging rates. Our results demonstrate that the storage voltage level strongly influences the degradation rate, with temperature playing a minor role. The identified aging effects include loss of active material on the cathode side and loss of lithium inventory. Initial degradation follows a urn:x-wiley:21960216:media:celc202400020:celc202400020-math-0001 -trajectory but is caused by overhang effects. The long-term aging is rather linear. |
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| 773 | _ | _ | |a 10.1002/celc.202400020 |g p. e202400020 |0 PERI:(DE-600)2724978-5 |n 9 |p e202400020 |t ChemElectroChem |v 11 |y 2024 |x 2196-0216 |
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