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@ARTICLE{Desmaizieres:1025930,
      author       = {Desmaizieres, Gauthier and Perner, Verena and Wassy, Daniel
                      and Kolek, Martin and Bieker, Peter and Winter, Martin and
                      Esser, Birgit},
      title        = {{E}valuating the {P}olymer {B}ackbone – {V}inylene versus
                      {S}tyrene – of {A}nisyl‐substituted {P}henothiazines as
                      {B}attery {E}lectrode {M}aterials},
      journal      = {Batteries $\&$ supercaps},
      volume       = {6},
      number       = {2},
      issn         = {2566-6223},
      address      = {Weinheim},
      publisher    = {Wiley-VCH},
      reportid     = {FZJ-2024-03208},
      pages        = {e202200464},
      year         = {2023},
      abstract     = {Organic electrode materials are capable candidates for
                      next-generation greener energy storage solutions. One
                      advantage is that their electrochemical performance can be
                      tuned by structural modification. We herein investigate
                      anisyl-substituted poly(vinyl-) and
                      poly(styrylphenothiazines) as positive electrode materials
                      for dual-ion batteries. π-Interactions – characteristic
                      to phenothiazine redox polymers – are facilitated in the
                      poly(styrene) derivatives PSAPT and PSAPT-X-DVB due to the
                      longer spacing between phenothiazine units and polymer
                      backbone and lead to high cycling stabilities, but reduce
                      their specific capacities. In the poly(vinylenes), the
                      linear PVAPT shows high cycling stability but a
                      dissolution/redeposition mechanism, diminishing its
                      capacity, while the cross-linked X-PVAPT demonstrates high
                      cycling stabilities at specific capacities up to
                      81 mAh g−1 paired with an excellent rate performance,
                      where 10,000 cycles at 100 C rate proceed with $86 \%$
                      capacity retention.},
      cin          = {IEK-12},
      ddc          = {540},
      cid          = {I:(DE-Juel1)IEK-12-20141217},
      pnm          = {1221 - Fundamentals and Materials (POF4-122) / DFG project
                      230408635 - Entwicklung organischer Materialien zur
                      Energiespeicherung, für elektrooptische Anwendungen und als
                      Template für neuartige Nanoröhren (230408635) / DFG
                      project 398214985 - Heteroaromatische Redoxpolymere für
                      Lithium-/organische Batterien (HALO) (398214985) / DFG
                      project 390874152 - EXC 2154: POLiS - Post Lithium Storage
                      Cluster of Excellence (390874152)},
      pid          = {G:(DE-HGF)POF4-1221 / G:(GEPRIS)230408635 /
                      G:(GEPRIS)398214985 / G:(GEPRIS)390874152},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000905832600001},
      doi          = {10.1002/batt.202200464},
      url          = {https://juser.fz-juelich.de/record/1025930},
}