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@ARTICLE{Ibing:1025931,
author = {Ibing, Lukas and Gallasch, Tobias and Göken, Vinzenz and
Niehoff, Philip and Winter, Martin and Börner, Markus},
title = {{M}aking {A}queously {P}rocessed {L}i{N}i 0.5 {M}n 0.3 {C}o
0.2 {O} 2 -{B}ased {E}lectrodes {C}ompetitive in
{P}erformance: {T}ailoring {D}istribution and
{I}nterconnection of {A}ctive and {I}nactive {E}lectrode
{M}aterials through {P}aste {S}urfactants},
journal = {ACS applied energy materials},
volume = {5},
number = {11},
issn = {2574-0962},
address = {Washington, DC},
publisher = {ACS Publications},
reportid = {FZJ-2024-03209},
pages = {13155 - 13160},
year = {2022},
abstract = {Enabling aqueous processing of positive active materials to
replace toxicologically critical N-methyl-2-pyrrolidone
could significantly reduce the ecologic and economic
footprint of lithium ion battery production. Processing
additives are key to elevate the performance of aqueously
processed electrodes beyond the state of the art. A mostly
neglected factor during aqueous processing is electrostatic
repulsion of active/inactive materials due to their ζ
potentials, which can be compensated for by applying
optimized amounts of surfactants like
hexadecyltrimethylammonium bromide. The notably improved
distribution and interconnection of active/inactive
materials lead to superior rate capability and similar
capacity retention during long-term cycling compared to
state-of-the-art processing.},
cin = {IEK-12},
ddc = {540},
cid = {I:(DE-Juel1)IEK-12-20141217},
pnm = {1221 - Fundamentals and Materials (POF4-122)},
pid = {G:(DE-HGF)POF4-1221},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000880839400001},
doi = {10.1021/acsaem.2c02755},
url = {https://juser.fz-juelich.de/record/1025931},
}