Hauptseite > Publikationsdatenbank > Hydrogen Bonding Competition Mediated Phase Separation with Abnormal Moisture‐Induced Stiffness Boosting > print

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024 7 _ |a 10.1002/smll.202401164
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100 1 _ |a Xu, Jian
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245 _ _ |a Hydrogen Bonding Competition Mediated Phase Separation with Abnormal Moisture‐Induced Stiffness Boosting
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520 _ _ |a Moisture usually deteriorates polymers’ mechanical performance owing to its plasticizing effect, causing side effects in their practical load-bearing applications. Herein, a simple binary ionogel consisting of an amphiphilic polymer network and a hydrophobic ionic liquid (IL) is developed with remarkable stiffening effect after moisture absorption, demonstrating a complete contrast to water-induced softening effect of most polymer materials. Such a moisture-induced stiffening behavior is induced by phase separation after hydration of this binary ionogel. Specifically, it is revealed that hydrogen (H)-bonding structures play a dominant role in the humidity-responsive behavior of the ionogel, where water will preferentially interact with polymer chains through H-bonding and break the polymer-IL H-bonds, thus leading to phase separation structures with modulus boosting. This work may provide a facile and effective molecular engineering route to construct mechanically adaptive polymers with water-induced dramatic stiffening for diverse applications.
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700 1 _ |a Hou, Lei
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700 1 _ |a Wu, Peiyi
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