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@ARTICLE{Banik:1026179,
      author       = {Banik, Ananya and Samanta, Bibek and Helm, Bianca and
                      Kraft, Marvin and Rudel, Yannik and Li, Cheng and Hansen,
                      Michael Ryan and Lotsch, Bettina V. and Bette, Sebastian and
                      Zeier, Wolfgang G.},
      title        = {{E}xploring {L}ayered {D}isorder in
                      {L}ithium-{I}on-{C}onducting
                      ${L}i_3{Y}_{1–x}{I}n_x{C}l_6$},
      journal      = {Inorganic chemistry},
      volume       = {63},
      number       = {19},
      issn         = {0020-1669},
      address      = {Washington, DC},
      publisher    = {American Chemical Society},
      reportid     = {FZJ-2024-03327},
      pages        = {86988709},
      year         = {2024},
      abstract     = {Li3Y1–xInxCl6 undergoes a phase transition from trigonal
                      to monoclinic via an intermediate orthorhombic phase.
                      Although the trigonal yttrium containing the end member
                      phase, Li3YCl6, synthesized by a mechanochemical route, is
                      known to exhibit stacking fault disorder, not much is known
                      about the monoclinic phases of the serial composition
                      Li3Y1–xInxCl6. This work aims to shed light on the
                      influence of the indium substitution on the phase evolution,
                      along with the evolution of stacking fault disorder using
                      X-ray and neutron powder diffraction together with
                      solid-state nuclear magnetic resonance spectroscopy,
                      studying the lithium-ion diffusion. Although Li3Y1–xInxCl6
                      with x ≤ 0.1 exhibits an ordered trigonal structure like
                      Li3YCl6, a large degree of stacking fault disorder is
                      observed in the monoclinic phases for the x ≥ 0.3
                      compositions. The stacking fault disorder materializes as a
                      crystallographic intergrowth of faultless domains with
                      staggered layers stacked in a uniform layer stacking, along
                      with faulted domains with randomized staggered layer
                      stacking. This work shows how structurally complex even the
                      “simple” series of solid solutions can be in this class
                      of halide-based lithium-ion conductors, as apparent from
                      difficulties in finding a consistent structural descriptor
                      for the ionic transport.},
      cin          = {IEK-12},
      ddc          = {540},
      cid          = {I:(DE-Juel1)IEK-12-20141217},
      pnm          = {1221 - Fundamentals and Materials (POF4-122)},
      pid          = {G:(DE-HGF)POF4-1221},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {38688036},
      UT           = {WOS:001227933500001},
      doi          = {10.1021/acs.inorgchem.4c00229},
      url          = {https://juser.fz-juelich.de/record/1026179},
}