TY  - JOUR
AU  - Ünal, Leyla
AU  - Maccio-Figgemeier, Viviane
AU  - Gebresilassie Eshetu, Gebrekidan
AU  - Figgemeier, Egbert
TI  - In‐Vitro Electrochemical Prelithiation: A Key Performance‐Boosting Strategy for Carbon Nanotube‐Containing Silicon‐Based Negative Electrodes in Li‐Ion Batteries
JO  - ChemElectroChem
VL  - 11
IS  - 17
SN  - 2196-0216
CY  - Weinheim
PB  - Wiley-VCH
M1  - FZJ-2024-03534
SP  - e202400146
PY  - 2024
N1  - The authors acknowledge the Federal Ministry of Education and Research of Germany (BMBF) for funding this work through the projects, PräLi (03XP0238X) and ProMIZ (13XP0397B). Open-Access funding enabled and organized by Projekt DEAL.
AB  - Prelithiation technology has emerged as an enabling approach towards the practical deployment of Silicon negative electrode-based Li-Ion batteries, leading to significant advancement in initial Coulombic efficiency (ICE), energy density and cycle life. In this study, an electrochemical prelithiation has been applied to Multi-Walled Carbon Nanotubes (MWCNTs)-containing Silicon-rich Silicon/Graphite-based negative electrode, eliminating almost ~51.03 % of its first irreversible capacity losses. In contrast, a benchmarking negative electrode utilizing Carbon black (Super P) as conductive additive is found to demonstrate a reduction of ~39.55 % after prelithiation, which is considerably lower compared to MWCNTs-based electrode system. Post-mortem analysis using Energy-dispersive X-ray (EDX) analysis with a Scanning Electron Microscope (SEM) and Attenuated Total Reflection Fourier Transform Infrared Spectroscopy (ATR-FTIR) shows disparities between pristine-cycled and prelithiated-cycled negative electrodes. Overall, prelithiation enabled MWCNTs can be regarded as an essential additive component in Silicon-based negative electrode systems for high-energy density Li-Ion batteries.
LB  - PUB:(DE-HGF)16
UR  - <Go to ISI:>//WOS:001234783100001
DO  - DOI:10.1002/celc.202400146
UR  - https://juser.fz-juelich.de/record/1026942
ER  -