TY  - JOUR
AU  - Fiedler, Magdalena
AU  - Lange, Martin A.
AU  - Hippauf, Felix
AU  - Dörfler, Susanne
AU  - Althues, Holger
AU  - Zeier, Wolfgang G.
AU  - Kaskel, Stefan
TI  - The role of nanoporous carbon materials for thiophosphate-based all solid state lithium sulfur battery performance
JO  - Carbon
VL  - 227
SN  - 0008-6223
CY  - Amsterdam [u.a.]
PB  - Elsevier Science
M1  - FZJ-2024-03735
SP  - 119252
PY  - 2024
N1  - This research and development results are funded by the German Federal Ministry of Education and Research (BMBF) within the SoLiS project (Grant No. 03XP0395) and AReLiS-3 project (03XP0595).
AB  - Due to their high theoretical energy density, all solid state lithium sulfur batteries (LS-SSB) represent one of the most promising candidates for next-generation energy storage systems. Whilst high sulfur utilizations have been published for several cathode compositions and preparation methods in recent years, there is still a lack of clarity regarding the influence of the used carbon. Furthermore, LS-SSBs face challenges in up-scaling as the common preparation methods including high energy ball milling are time consuming, batch-wise and need high energy impact. In this study, high sulfur utilization >1600 mAh g$_S^{−1}$ and reversibility with 80 % of initial discharge capacity after 60 cycles is achieved, using a more time-efficient preparation method with drastically lowered energy impact by selecting a suitable carbon. Additionally, the influence of the carbon nanostructure on the electrochemical performance is discussed. This study provides guidance in selecting nanostructured carbon materials to enable cost-efficient, up-scalable preparation methods for LS-SSBs without compromising on the excellent electrochemical performance.
LB  - PUB:(DE-HGF)16
UR  - <Go to ISI:>//WOS:001292111100001
DO  - DOI:10.1016/j.carbon.2024.119252
UR  - https://juser.fz-juelich.de/record/1027304
ER  -