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@ARTICLE{Fiedler:1027304,
author = {Fiedler, Magdalena and Lange, Martin A. and Hippauf, Felix
and Dörfler, Susanne and Althues, Holger and Zeier,
Wolfgang G. and Kaskel, Stefan},
title = {{T}he role of nanoporous carbon materials for
thiophosphate-based all solid state lithium sulfur battery
performance},
journal = {Carbon},
volume = {227},
issn = {0008-6223},
address = {Amsterdam [u.a.]},
publisher = {Elsevier Science},
reportid = {FZJ-2024-03735},
pages = {119252},
year = {2024},
note = {This research and development results are funded by the
German Federal Ministry of Education and Research (BMBF)
within the SoLiS project (Grant No. 03XP0395) and AReLiS-3
project (03XP0595).},
abstract = {Due to their high theoretical energy density, all solid
state lithium sulfur batteries (LS-SSB) represent one of the
most promising candidates for next-generation energy storage
systems. Whilst high sulfur utilizations have been published
for several cathode compositions and preparation methods in
recent years, there is still a lack of clarity regarding the
influence of the used carbon. Furthermore, LS-SSBs face
challenges in up-scaling as the common preparation methods
including high energy ball milling are time consuming,
batch-wise and need high energy impact. In this study, high
sulfur utilization >1600 mAh g$_S^{−1}$ and reversibility
with 80 \% of initial discharge capacity after 60 cycles is
achieved, using a more time-efficient preparation method
with drastically lowered energy impact by selecting a
suitable carbon. Additionally, the influence of the carbon
nanostructure on the electrochemical performance is
discussed. This study provides guidance in selecting
nanostructured carbon materials to enable cost-efficient,
up-scalable preparation methods for LS-SSBs without
compromising on the excellent electrochemical performance.},
cin = {IEK-12},
ddc = {540},
cid = {I:(DE-Juel1)IEK-12-20141217},
pnm = {1222 - Components and Cells (POF4-122)},
pid = {G:(DE-HGF)POF4-1222},
typ = {PUB:(DE-HGF)16},
UT = {WOS:001292111100001},
doi = {10.1016/j.carbon.2024.119252},
url = {https://juser.fz-juelich.de/record/1027304},
}