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@PHDTHESIS{Schwiers:1028395,
      author       = {Schwiers, Alexander},
      title        = {{I}nvestigation and implementation of improved and
                      degradation-tolerant fuel electrodes for solid oxide cells},
      volume       = {634},
      school       = {RWTH Aachen University},
      type         = {Dissertation},
      address      = {Jülich},
      publisher    = {Forschungszentrum Jülich GmbH Zentralbibliothek, Verlag},
      reportid     = {FZJ-2024-04576},
      isbn         = {978-3-95806-762-2},
      series       = {Schriften des Forschungszentrums Jülich Reihe Energie $\&$
                      Umwelt / Energy $\&$ Environment},
      pages        = {VI, 163, XIII},
      year         = {2024},
      note         = {Dissertation, RWTH Aachen University, 2024},
      abstract     = {Ni- yttria-stabilized zirconia is commonly used as a fuel
                      electrode cermet in solid oxide cells due to its compelling
                      combination of conductivity, stability, and material
                      compatibility. However, it faces significant degradation
                      when exposed to hydrocarbon-rich fuels, such as
                      tar-containing biogas. Carbon adsorption poisons the Ni
                      component, leading to a decrease in catalytic activity,
                      while the formation of carbon fibers ultimately results in
                      nickel dusting. To address the issue of fuel electrode
                      degradation without the need for fuel pre-treatment, this
                      study investigates two alternative fuel electrode materials.
                      The first material is gadolinia-doped ceria
                      (Gd0.1Ce0.9O2-δ) as a replacement for yttria-stabilized
                      zirconia. Gadolinia-doped ceria possesses mixed electronic
                      and ionic conductivity, allowing it to maintain catalytic
                      activity even when Ni is poisoned. Moreover, it exhibits
                      oxygen storage capacity, potentially aiding in carbon
                      removal. ...},
      cin          = {IEK-1 / IMD-2},
      cid          = {I:(DE-Juel1)IEK-1-20101013 / I:(DE-Juel1)IMD-2-20101013},
      pnm          = {1231 - Electrochemistry for Hydrogen (POF4-123)},
      pid          = {G:(DE-HGF)POF4-1231},
      typ          = {PUB:(DE-HGF)3 / PUB:(DE-HGF)11},
      doi          = {10.34734/FZJ-2024-04576},
      url          = {https://juser.fz-juelich.de/record/1028395},
}