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@INPROCEEDINGS{Qdemat:1028694,
author = {Qdemat, Asmaa and Kentzinger, Emmanuel and Buitenhuis,
Johan and Pütter, Sabine and Hussein, Mai and
Bednarski-Meinke, Connie and Seidel, Nadine and Petracic,
Oleg and Rücker, Ulrich and Brückel, Thomas},
title = {{C}urvature-modulated structural and magnetic properties of
thin filmsdeposited onto highly ordered nanosphere arrays},
reportid = {FZJ-2024-04751},
year = {2024},
abstract = {The magnetic interaction among magnetic nanostructures has
garnered significant attention, leading to extensive
research on magneticnanocaps. This exciting research trend
has motivated us to explore the potential of these
structures. We successfully fabricated andcharacterized
isolated and interconnected magnetic nanocaps by depositing
magnetic thin films on highly ordered arrays of nanospheres.
Theuse of curved surfaces as substrates causes lateral
variations in film thickness, resulting in varying deposited
material properties. Multilayers ofCo/Pd with varying Co
thicknesses were deposited using Molecular Beam Epitaxy
(MBE) on a flat silicon (Si) substrate and on densely
packedtwo-dimensional arrays of silica nanospheres with
diameters of 50 nm and 200 nm, formed using an improved
drop-casting method [1]. Themagnetic and structural
properties of the nanostructures obtained were compared to
those of films deposited simultaneously on a bare
Sisubstrate (reference film). Both the studied film and the
reference film were grown polycrystalline, while their
roughness, as observed from X-rayreflectivity, differed
significantly. X-ray reflectivity revealed that the
reference films displayed well-defined Kiessig oscillations,
indicating lowroughness in the deposited films. In contrast,
the films on nanospheres conformed to the curvature of the
underlying nanospheres and exhibiteda systematic periodic
variation, resulting in the absence of Kiessig oscillations.
Magnetic measurements using SQUID confirmed the formationof
magnetic nanocaps as they exhibited distinct magnetic
properties, including a different anisotropy axis direction
and a drastically highcoercivity with increasing film
thickness, compared to the flat films prepared on a bare Si
substrate. Furthermore, Grazing Incidence Small AngleX-ray
Scattering (GISAXS) confirms the formation of a
well-aligned, uniform nanosphere distribution. Additionally,
the depth-resolved profile ofthe magnetization was studied
using Polarized Neutron Reflectivity (PNR). The overall
results, the magnetic and structural properties of the
thinfilms were correlated as a function of film thickness
and nanosphere radius.SEM and GISAXS of (left) densely
packed two-dimensional arrays of monodisperse spherical
silica particles and (right) self-assembled particle arrays
after magnetic film depositionReferences[1] A. Qdemat,
et.al., RSC Adv., 10 (2020) 18339-18347},
month = {Jun},
date = {2024-06-30},
organization = {22nd International Conference on
Magnetism, Bologna (Italien), 30 Jun
2024 - 5 Jul 2024},
subtyp = {Invited},
cin = {JCNS-2 / JARA-FIT / IBI-4 / JCNS-4 / JCNS-HBS},
cid = {I:(DE-Juel1)JCNS-2-20110106 / $I:(DE-82)080009_20140620$ /
I:(DE-Juel1)IBI-4-20200312 / I:(DE-Juel1)JCNS-4-20201012 /
I:(DE-Juel1)JCNS-HBS-20180709},
pnm = {632 - Materials – Quantum, Complex and Functional
Materials (POF4-632) / 6G4 - Jülich Centre for Neutron
Research (JCNS) (FZJ) (POF4-6G4)},
pid = {G:(DE-HGF)POF4-632 / G:(DE-HGF)POF4-6G4},
typ = {PUB:(DE-HGF)6},
url = {https://juser.fz-juelich.de/record/1028694},
}