TY - JOUR
AU - Strozecka, A.
AU - Muthukumar, K.
AU - Dybek, A.
AU - Dennis, J.
AU - Larsson, A.
AU - Myslivecek, J.
AU - Voigtländer, B.
TI - Modification of the conductance of single fullerene molecules by endohedral doping
JO - Applied physics letters
VL - 95
SN - 0003-6951
CY - Melville, NY
PB - American Institute of Physics
M1 - PreJuSER-10292
SP - 133118
PY - 2009
N1 - This work was supported by the FP6 project NANO-CAGE (Grant No. MEST-CT-2004-50-6854), the Science Foundation of Ireland, and Czech Project MSM Grant No. 0021620834. We acknowledge the Irish Centre for High-End Computing (ICHEC) for generous allotment of computer resources.
AB - We use scanning tunneling microscopy to establish controlled contacts to single molecules of endohedrally doped Ce-2@C-80 fullerenes with C-60 as a reference. The stability of the experimental setup allows for the determination of the conductance of Ce-2@C-80 relative to the conductance of C-60. The endohedral doping reduces the conductance of Ce-2@C-80 by a factor of about five with respect to C-60. Ab initio calculations show that the reason for this reduced conductance is the absence of electron orbitals delocalized over the cage of Ce-2@C-80 in the energy window of the conductance measurement. (C) 2009 American Institute of Physics. [doi:10.1063/1.3236529]
KW - J (WoSType)
LB - PUB:(DE-HGF)16
UR - <Go to ISI:>//WOS:000270458000064
DO - DOI:10.1063/1.3236529
UR - https://juser.fz-juelich.de/record/10292
ER -