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@ARTICLE{Whang:1030111,
      author       = {Whang, Grace and Ketter, Lukas and Zhao, Tong and
                      Nazmutdinova, Elina and Kraft, Marvin A. and Zeier, Wolfgang
                      G.},
      title        = {{H}igh {A}real {C}apacity {C}ation and {A}nionic {R}edox
                      {S}olid-{S}tate {B}atteries {E}nabled by {T}ransition
                      {M}etal {S}ulfide {C}onversion},
      journal      = {ACS applied materials $\&$ interfaces},
      volume       = {16},
      number       = {32},
      issn         = {1944-8244},
      address      = {Washington, DC},
      publisher    = {Soc.},
      reportid     = {FZJ-2024-05224},
      pages        = {42189 - 42197},
      year         = {2024},
      note         = {Funding by: BMBF project "MaSSiF" (03XP0519C)},
      abstract     = {Pure sulfur ($S_8$ and $Li_2S$) all solid-state batteries
                      inherently suffer from low electronic conductivities,
                      requiring the use of carbon additives, resulting in
                      decreased active material loading at the expense of
                      increased loading of the passive components. In this work, a
                      transition metal sulfide in combination with lithium
                      disulfide is employed as a dual cation–anion redox
                      conversion composite cathode system. The transition metal
                      sulfide undergoes cation redox, enhancing the electronic
                      conductivity, whereas the lithium disulfide undergoes anion
                      redox, enabling high-voltage redox conducive to achieving
                      high energy densities. Carbon-free cathode composites with
                      active material loadings above 6.0 mg cm–2 attaining areal
                      capacities of ∼4 mAh cm–2 are demonstrated with the
                      possibility to further increase the active mass loading
                      above 10 mg cm–2 achieving cathode areal capacities above
                      6 mAh cm–2, albeit with less cycle stability. In addition,
                      the effective partial transport and thermal properties of
                      the composites are investigated to better understand
                      $FeS:Li_2S$ cathode properties at the composite level. The
                      work introduced here provides an alternative route and
                      blueprint toward designing new dual conversion cathode
                      systems, which can operate without carbon additives enabling
                      higher active material loadings and areal capacities.},
      cin          = {IMD-4},
      ddc          = {600},
      cid          = {I:(DE-Juel1)IMD-4-20141217},
      pnm          = {1223 - Batteries in Application (POF4-122) / DFG project
                      G:(GEPRIS)459785385 - Röntgenpulverdiffraktometer
                      (459785385)},
      pid          = {G:(DE-HGF)POF4-1223 / G:(GEPRIS)459785385},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {39093830},
      UT           = {WOS:001284141700001},
      doi          = {10.1021/acsami.4c07252},
      url          = {https://juser.fz-juelich.de/record/1030111},
}