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@INPROCEEDINGS{Meven:1030415,
author = {Meven, Martin and Redhammer, G. and Rettenwander, D. and
Ceretti, M. and Paulus, W. and Bosak, A.},
title = {{S}ingle {C}rystal {D}iffraction {S}tudies on {E}nergy
{S}torage {M}aterials with {H}ot {N}eutrons on {HE}i{D}i},
reportid = {FZJ-2024-05288},
year = {2024},
abstract = {The single crystal diffractometer HEiDi (jointly operated
by RWTH Aachen University and the Forschungszentrum Jülich)
at the research neutron source FRM II at the Heinz
Maier-Leibnitz Zentrum (MLZ) in Garching offers a broad
spectrum of thermal and hot neutrons, high neutron flux,
high resolution and a large access to reciprocal space, low
absorption and high sensitivity for light elements.
Especially its last features makes HEiDi a valuable tool for
extended studies on different materials and components
relevant for applications in the field of energy research.
Lithium is one of the most important ingredients of nowadays
batteries. Further improvements depend on better components,
e.g. those that offer higher energy densities and higher
operational reliability. Solid-state electrolytes, based on
the cubic garnet Li$_6$La$_3$ZrTaO$_{12}$ (LLZTO), are
potential candidates and have become the focus of research
recently. A comprehensive T dependent study using single
crystal neutron and x-ray diffraction technique (2.5 K ≤ T
≤ 873 K) delivers new insights in the mobility and
pathways of the Li ions in this complex structure [1, 2,
3].Another important example are oxygen diffusion pathways
in various brownmillerites, like Nd$_2$NiO$_{4+\delta}$ or
Pr$_2$NiO$_{4+\delta}$ [4]. The introduction of interstitial
oxygen affects not only the electric and structural
properties but also the magnetic ones of these compounds.
Within a joint French-German project (DFG funding ME
3488/2-1), a special mirror furnace –built at the FRM II
–allowed detailed studies on the oxygen behavior up to
1300 K and in various sample atmospheres with different
oxygen concentrations and pressures. Other neutron studies
studies were performed down to ~2.5K inorder to get insights
into the relationship between (weak) oxygen doping and
magnetic order [5, 6] These experiments were combined with
elastic and inelastic synchrotron radiation to gain a
complete overview of the oxygen (dis)orders and phase
transitions.[1] G.J. Redhammer, M. Meven, S. Ganschow, G.
Tippelt and D. Rettenwander; Acta Cryst. B 77(2021),
123-130; https://doi.org/10.1107/S2052520620016145[2] G.J.
Redhammer, P. Badami, M. Meven, S. Ganschow, S. Berendts, G.
Tippelt, and D. Rettenwander; ACS Appl. Mater. Interfaces
(2021), 350–359; https://doi.org/10.1021/acsami.0c16016[3]
M. Philipp, B. Gadermaier, P. Posch, I. Hanzu, S. Ganschow,
M. Meven, D. Rettenwander, G.J. Redhammer, H. Martin R.
Wilkening; Adv. Mater. Interfaces 7 (2020), 200450;
https://doi.org/10.1002/admi.202000450[4] C. Hareesh, M.
Ceretti, P. Papet, A. Bosak, M. Meven and W. Paulus;
Crystals 13(12), 1670;
https://doi.org/10.3390/cryst13121670[5] S.R. Maity, M.
Ceretti, L. Keller, J. Schefer, M. Meven, E. Pomjakushina,
and W. Paulus; Phys. Rev. Materials 5 (2021), 014401;
https://doi.org/10.1103/PhysRevMaterials.5.014401[6] S.R.
Maity, M. Ceretti, L. Keller, J. Schefer, T. Shang, E.
Pomjakushina, M. Meven, D. Sheptyakov, A. Cervellino and W.
Paulus; Phys. Rev. Materials 3 (2019), 083604;
https://doi.org/10.1103/PhysRevMaterials.3.083604},
month = {Jun},
date = {2024-06-04},
organization = {MLZ Conference 2024: Neutrons for
Energy Storage, Munich (Germany), 4 Jun
2024 - 7 Jun 2024},
subtyp = {After Call},
cin = {JCNS-FRM-II / MLZ / JARA-FIT / JCNS-2 / JCNS-4},
cid = {I:(DE-Juel1)JCNS-FRM-II-20110218 / I:(DE-588b)4597118-3 /
$I:(DE-82)080009_20140620$ / I:(DE-Juel1)JCNS-2-20110106 /
I:(DE-Juel1)JCNS-4-20201012},
pnm = {6G4 - Jülich Centre for Neutron Research (JCNS) (FZJ)
(POF4-6G4) / 632 - Materials – Quantum, Complex and
Functional Materials (POF4-632) / DFG project 431446509 -
Untersuchung der Sauerstoff-Diffusionsmechanismen in
Pr2NiO4+d unter in situ-Bedingungen mittels
Neutronenstreuung: Wechselwirkung zwischen Struktur und
Gitterdynamik (431446509)},
pid = {G:(DE-HGF)POF4-6G4 / G:(DE-HGF)POF4-632 /
G:(GEPRIS)431446509},
experiment = {EXP:(DE-MLZ)HEIDI-20140101},
typ = {PUB:(DE-HGF)6},
url = {https://juser.fz-juelich.de/record/1030415},
}