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001031177 245__ $$aSynergistic Enhancement of Mechanical and Electrochemical Properties in Grafted Polymer/Oxide Hybrid Electrolytes
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001031177 520__ $$aLithium metal batteries operated with high voltage cathodes are predestined for the realization of high energy storage systems, where solid polymer electrolytes offer a possibility to improve battery safety. Al2O3_PCL is introduced as promising hybrid electrolyte made from polycaprolactone (PCL) and Al2O3 nanoparticles that can be prepared in a one-pot synthesis as a random mixture of linear PCL and PCL-grafted Al2O3. Upon grafting, synergistic effects of mechanical stability and ionic conductivity are achieved. Due to the mechanical stability, manufacture of PCL-based membranes with a thickness of 50 µm is feasible, yielding an ionic conductivity of 5·10−5 S cm−1 at 60 °C. The membrane exhibits an impressive performance of Li deposition in symmetric Li||Li cells, operating for 1200 h at a constant and low overvoltage of 54 mV and a current density of 0.2 mA cm−2. NMC622 | Al2O3_PCL | Li cells are cycled at rates of up to 1 C, achieving 140 cycles at >80% state of health. The straightforward synthesis and opportunity of upscaling as well as solvent-free polymerization render the Al2O3_PCL hybrid material as rather safe, potentially sustainable and affordable alternative to conventional polymer-based electrolytes.
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001031177 7001_ $$0P:(DE-Juel1)194100$$aKrude, Annalena$$b1$$ufzj
001031177 7001_ $$0P:(DE-Juel1)164855$$aLennartz, Peter$$b2
001031177 7001_ $$00009-0000-4743-4947$$aClausnitzer, Moritz$$b3
001031177 7001_ $$00009-0002-6259-3377$$aShukla, Gourav$$b4
001031177 7001_ $$0P:(DE-Juel1)180325$$aBuchheit, Annika$$b5
001031177 7001_ $$aKempe, Fabian$$b6
001031177 7001_ $$0P:(DE-Juel1)169877$$aDiddens, Diddo$$b7
001031177 7001_ $$0P:(DE-Juel1)195918$$aGlomb, Pascal$$b8$$ufzj
001031177 7001_ $$0P:(DE-Juel1)192389$$aMitchell, Melanie M.$$b9$$ufzj
001031177 7001_ $$00000-0003-2336-6059$$aDanner, Timo$$b10
001031177 7001_ $$0P:(DE-Juel1)176646$$aHeuer, Andreas$$b11$$ufzj
001031177 7001_ $$00000-0003-1449-8172$$aLatz, Arnulf$$b12
001031177 7001_ $$0P:(DE-Juel1)166130$$aWinter, Martin$$b13$$ufzj
001031177 7001_ $$0P:(DE-Juel1)172047$$aBrunklaus, Gunther$$b14
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