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@ARTICLE{Whang:1032474,
      author       = {Whang, Grace and Huang, Jake and Le Pham, Phuong Nam and
                      Kraft, Marvin and Zeier, Wolfgang},
      title        = {{N}ot {A}ll {L}ithium–{I}ndium {C}ounter {E}lectrodes
                      {A}re {M}ade {E}qual: {P}robing the {I}nhomogeneities and
                      {K}inetics of {U}niaxially {P}ressed {L}i–{I}n {C}ounter
                      {E}lectrodes in {A}ll {S}olid-{S}tate {B}atteries},
      journal      = {ACS electrochemistry},
      volume       = {1},
      number       = {2},
      issn         = {2997-0571},
      address      = {Washington, DC},
      publisher    = {ACS Publications},
      reportid     = {FZJ-2024-06267},
      pages        = {249–262},
      year         = {2025},
      abstract     = {Lithium indium alloys are commonly used as
                      counterelectrodes in all-solid-state batteries. However, the
                      method ofpreparation varies from research groups, including
                      ball milling, rollpressing, and uniaxial pressing of the two
                      metals. While the latter is acommon approach used in the
                      literature, it is not entirely clear howhomogeneous
                      uniaxially pressed counter electrodes are and whetherthe
                      differences can be observed electrochemically. In this work,
                      in thefirst section, two distinct Li sources, one from the
                      chemical Li−In alloyand the other from the electrochemical
                      Li−In alloy formed duringcycling, are electrochemically
                      probed and investigated as a function ofthe temperature,
                      indium foil thickness, and Li area. In the secondsection,
                      the kinetics of electrochemically alloyed Li−In
                      ($e-Li_xIn$) areinvestigated using Butler-Volmer kinetics to
                      extrapolate exchange current densities in combination with
                      time and temperature-dependent distribution of relaxation
                      time (DRT) analyses to better understand the alloying and
                      dealloying process. These findingsunderscore the
                      considerable influence that counter electrode preparation
                      has on the kinetics and electrochemical performance of
                      twoelectrode half-cells.},
      cin          = {IMD-4},
      ddc          = {660},
      cid          = {I:(DE-Juel1)IMD-4-20141217},
      pnm          = {1221 - Fundamentals and Materials (POF4-122) / DFG project
                      G:(GEPRIS)459785385 - Röntgenpulverdiffraktometer
                      (459785385) / MASSIF - Modifying All Solid State Lithium
                      Battery Interfaces (101029499)},
      pid          = {G:(DE-HGF)POF4-1221 / G:(GEPRIS)459785385 /
                      G:(EU-Grant)101029499},
      typ          = {PUB:(DE-HGF)16},
      doi          = {10.1021/acselectrochem.4c00060},
      url          = {https://juser.fz-juelich.de/record/1032474},
}