% IMPORTANT: The following is UTF-8 encoded. This means that in the presence
% of non-ASCII characters, it will not work with BibTeX 0.99 or older.
% Instead, you should use an up-to-date BibTeX implementation like “bibtex8” or
% “biber”.
@INPROCEEDINGS{Frielinghaus:1034076,
author = {Frielinghaus, Henrich},
title = {{S}tructure and dynamics of a quasi-binary liquid in 2 and
3 dimensions},
reportid = {FZJ-2024-06897},
year = {2024},
abstract = {We investigated a quasi-binary liquid of 3-methyl pyridine
and heavy water at the critical composition at different
temperatures close to the phase transition. When adding
antagonistic salt sodium tetraphenylborate the ions form
locally lamellar structures that enclose the binary fluid.
Then the system becomes 2-dimensional. Looking at the
critical fluctuations, the dimensionality is confirmed. The
dynamics of the 3 and 2-dimensional system displays
diffusion on large length scales (dynamic light scattering)
and fluctuations of the boundaries between the domains on
small length scales (neutron spin echo spectroscopy). From
that we obtain a master curve following the theory of
Kawasaki. On the one hand the critical exponent is obtained
that can be rationalized by theoretical concepts. The
overall prefactor of the master curve displays approx. 2
times faster diffusion for the 2-dimensional compared to the
3-dimensional system. This can be explained by much lower
viscosities (also measured) of the 2-dimensional system.
This is theoretically explained by the lubrication
effect.Looking at the high- scattering, we determined the
critical correlation-function exponent that is
extraordinarily large for the 2-dimensional system. It seems
that the composition fluctuations in the 2 dimensions and
the 3rd dimension are orientationally averaged.A short
excursion will also look on an aerogel as porous material
that interferes with the binary fluid.},
month = {Dec},
date = {2024-12-05},
organization = {MLZ User Meeting 2024, Munich
(Germany), 5 Dec 2024 - 6 Dec 2024},
subtyp = {Outreach},
cin = {JCNS-FRM-II / JCNS-4 / MLZ},
cid = {I:(DE-Juel1)JCNS-FRM-II-20110218 /
I:(DE-Juel1)JCNS-4-20201012 / I:(DE-588b)4597118-3},
pnm = {6G4 - Jülich Centre for Neutron Research (JCNS) (FZJ)
(POF4-6G4) / 632 - Materials – Quantum, Complex and
Functional Materials (POF4-632)},
pid = {G:(DE-HGF)POF4-6G4 / G:(DE-HGF)POF4-632},
experiment = {EXP:(DE-MLZ)NOSPEC-20140101},
typ = {PUB:(DE-HGF)6},
url = {https://juser.fz-juelich.de/record/1034076},
}