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@ARTICLE{Knispel:1034174,
      author       = {Knispel, Timo and Mohrenstecher, Daniela and Speckmann,
                      Carsten and Safeer, Affan and van Efferen, Camiel and Boix,
                      Virgínia and Grüneis, Alexander and Jolie, Wouter and
                      Preobrajenski, Alexei and Knudsen, Jan and Atodiresei,
                      Nicolae and Michely, Thomas and Fischer, Jeison},
      title        = {{E}ngineering 2{D} {M}aterials from {S}ingle‐{L}ayer
                      {N}b{S} 2},
      journal      = {Small},
      volume       = {21},
      number       = {3},
      issn         = {1613-6810},
      address      = {Weinheim},
      publisher    = {Wiley-VCH},
      reportid     = {FZJ-2024-06985},
      pages        = {2408044},
      year         = {2025},
      abstract     = {Starting from a single layer of NbS2 grown on graphene by
                      molecular beam epitaxy, the single unit cell thick 2D
                      materials Nb5/3S3-2D and Nb2S3-2D are created using two
                      different pathways. Either annealing under sulfur-deficient
                      conditions at progressively higher temperatures or
                      deposition of increasing amounts of Nb at elevated
                      temperature result in phase-pure Nb5/3S3-2D followed by
                      Nb2S3-2D. The materials are characterized by scanning
                      tunneling microscopy, scanning tunneling spectroscopy, and
                      X-ray photoemission spectroscopy. The experimental
                      assessment combined with systematic density functional
                      theory calculations reveals their structure. The 2D
                      materials are covalently bound without any van der Waals
                      gap. Their stacking sequence and structure are at variance
                      with expectations based on corresponding bulk materials
                      highlighting the importance of surface and interface effects
                      in structure formation.},
      cin          = {PGI-1},
      ddc          = {620},
      cid          = {I:(DE-Juel1)PGI-1-20110106},
      pnm          = {5211 - Topological Matter (POF4-521) / SFB 1238 B06 -
                      Rastertunnelspektroskopie (B06) (319897474) / SFB 1238 C01 -
                      Strukturinversionsasymmetrische Materie und
                      Spin-Orbit-Phänomene mittels ab initio (C01) (319898210) /
                      SFB 1238 A01 - Konstruktion von 2D-Heterostrukturen für die
                      Kontrolle elektronischer, optischer und magnetischer
                      Eigenschaften (A01) (319464028) / DFG project
                      G:(GEPRIS)535290457 - Gezielte Herstellung von
                      Vielteilchenzuständen in zweidimensionalen
                      van-der-Waals-Heterostrukturen (535290457) / DFG project
                      G:(GEPRIS)462692705 - Antiskyrmionen auf Oberflächen durch
                      anisotrope Dzyaloshinskii-Moriya-Wechselwirkungen
                      (462692705)},
      pid          = {G:(DE-HGF)POF4-5211 / G:(GEPRIS)319897474 /
                      G:(GEPRIS)319898210 / G:(GEPRIS)319464028 /
                      G:(GEPRIS)535290457 / G:(GEPRIS)462692705},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {39584382},
      UT           = {WOS:001362082500001},
      doi          = {10.1002/smll.202408044},
      url          = {https://juser.fz-juelich.de/record/1034174},
}