Talk (non-conference) (Other) FZJ-2025-00374

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Praseodymium Doped Ceria as Nickel-free Fuel Electrode Material for Solid Oxide Electrolysis Cells

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2024

Sci & Hike Retreat, GermanyGermany,

Abstract: Solid oxide electrolysis cells (SOECs) are promising electrochemical conversion devices for Power-to-Gas technologies but face degradation issues with conventional nickel-based fuel electrodes (e.g. Ni-YSZ or Ni-GDC) at high current densities. This research investigates the potential of using praseodymium doped ceria (PDC) as a nickel-free alternative. For this purpose, three different materials were tested: 5% lanthanum and 5% praseodymium doped ceria (LPDC), 10% praseodymium doped ceria (PDC10), and 30% praseodymium doped ceria (PDC30). In an electrochemical performance evaluation under steam electrolysis conditions at 900°C, PDC10 outperformed both LPDC (-1.37 A/cm²) and PDC30 (-1.1 A/cm²), achieving a current density of -1.5 A/cm² at 1.5 V. Future work will include structural and electrochemical analysis of all three samples to evaluate their physico-chemical behavior at a fundamental level. In conclusion, these findings suggest that praseodymium-doped ceria could be a promising candidate for efficient and durable fuel electrode materials in SOECs.


Contributing Institute(s):
  1. Grundlagen der Elektrochemie (IET-1)
Research Program(s):
  1. 1232 - Power-based Fuels and Chemicals (POF4-123) (POF4-123)
  2. HITEC - Helmholtz Interdisciplinary Doctoral Training in Energy and Climate Research (HITEC) (HITEC-20170406) (HITEC-20170406)

Appears in the scientific report 2024
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 Record created 2025-01-09, last modified 2025-02-03



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