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@INPROCEEDINGS{Granwehr:1037565,
author = {Granwehr, Josef},
title = {{M}agnetic resonance of electrochemical components and
devices},
reportid = {FZJ-2025-00753},
year = {2025},
abstract = {Magnetic resonance (MR) is a powerful analytical tool in
electrochemistry due to its selectivity and versatility. If
studying materials for electrochemical applications, similar
opportunities and limitations exist as for other materials.
However, some established paradigms for data analysis and
interpretation need to be questioned for ion-conducting
materials with stochastic occupancy. Since
performance-limiting processes often occur at interfaces,
one would like to study working cells, ideally during
operation. In this case various additional challenges are
introduced, such as electrically conducting components that
cause losses in common MR setups, or changing impedances
during cycling and aging that alter the Q of the
resonator.In this talk, strategies will be discussed to
identify and mitigate some of these challenges. For some
questions, a compromise is offered by studying components of
electrochemical systems, where interfaces are present yet
losses can be minimised. NMR and EPR examples of battery
applications will be presented where sample preparation and
protocols are adapted to address specific questions. Laplace
inversion without non-negativity constraint is demonstrated
as a useful tool to analyse relaxation and diffusion data,
and the importance of an integrated approach combining MR
and theory for data interpretation is highlighted.},
month = {Jan},
date = {2025-01-17},
organization = {Konstantin Ivanov Intercontinental
Seminar, Online (France), 17 Jan 2025 -
17 Jan 2025},
subtyp = {Invited},
cin = {IET-1},
cid = {I:(DE-Juel1)IET-1-20110218},
pnm = {1223 - Batteries in Application (POF4-122) / DFG project
G:(GEPRIS)422726248 - SPP 2248: Polymer-basierte Batterien
(422726248) / InOPlaBat - In-Situ und Operando Plating
Detektion in Batterien (13XP0352B)},
pid = {G:(DE-HGF)POF4-1223 / G:(GEPRIS)422726248 /
G:(BMBF)13XP0352B},
typ = {PUB:(DE-HGF)31},
url = {https://juser.fz-juelich.de/record/1037565},
}