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@ARTICLE{Kong:1037614,
author = {Kong, Mengqin and Osvet, Andres and Forberich, Karen and
Barabash, Anastasia and Erban, Christof and Batentschuk,
Miroslaw and Brabec, Christoph},
title = {{L}ead-{F}ree {P}erovskite {C}s 2 {A}g x {N}a 1– x {B}i y
{I}n 1– y {C}l 6 {M}icrocrystals for
{S}cattering–{F}luorescent {L}uminescent {S}olar
{C}oncentrators},
journal = {ACS applied materials $\&$ interfaces},
volume = {17},
number = {1},
issn = {1944-8244},
address = {Washington, DC},
publisher = {Soc.},
reportid = {FZJ-2025-00785},
pages = {1644 - 1653},
year = {2025},
abstract = {In recent years, luminescent solar concentrators (LSCs)
have gained a renaissance as a pivotal transparent
photovoltaic (PV) for building-integrated photovoltaics
(BIPVs). However, most of the studies focused on
light-selective LSCs, and less attention was paid to the
utilization of the full solar spectrum. In this study, a
lead-free microcrystal Cs2AgxNa1–xBiyIn1–yCl6 (CANBIC)
perovskite phosphor is demonstrated to have bifunctional
effects of luminescent down-shifting (LDS) and light
scattering for the fabrication of LSCs, realizing light
response from ultraviolet (UV) to NIR regions by an
edge-mounted Si solar cell. The optimized CANBIC content (30
mg) in an LSC realizes the best optical efficiency (ηopt)
of $5.40\%$ and an average visible transmission (AVT) of
$>50\%.$ This contributes to the improvement in short
circuit current density (JSC) up to 1.232 mA/cm2 for the
LSC–PV system (one-edge mounted Si solar cell) as a result
of the best power conversion efficiencies (PCEs) of
$0.463\%$ and $1.852\%$ for the LSC–PV and LSC–4PV
systems (four-edge mounted Si solar cells), respectively. An
Al foil is applied as a reflection background in the
LSC–4PV system, and a champion PCE of $3.14\%$ is realized
due to an improved JSC of up to 7.94 mA/cm2 in total.
Furthermore, the LSC maintains superior stability under
exposure to continuous ultraviolet illumination or in
ambient air.},
cin = {IET-2},
ddc = {600},
cid = {I:(DE-Juel1)IET-2-20140314},
pnm = {1212 - Materials and Interfaces (POF4-121) / 1214 -
Modules, stability, performance and specific applications
(POF4-121)},
pid = {G:(DE-HGF)POF4-1212 / G:(DE-HGF)POF4-1214},
typ = {PUB:(DE-HGF)16},
pubmed = {39718808},
doi = {10.1021/acsami.4c18315},
url = {https://juser.fz-juelich.de/record/1037614},
}