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@ARTICLE{OrtegaRamrez:1037779,
author = {Ortega-Ramírez, Audrey Magdalena and Albani, Simone and
Bachmann, Michèle and Schmidt, Axel and Pinoé-Schmidt,
Manuela and Assmann, Marc and Augustinowski, Katrin and
Rossetti, Giulia and Gründer, Stefan},
title = {{A} conserved peptide-binding pocket in {H}y{N}a{C}/{ASIC}
ion channels},
journal = {Proceedings of the National Academy of Sciences of the
United States of America},
volume = {121},
number = {41},
issn = {0027-8424},
address = {Washington, DC},
publisher = {National Acad. of Sciences},
reportid = {FZJ-2025-00931},
pages = {e2409097121},
year = {2024},
abstract = {The only known peptide-gated ion channels—FaNaCs/WaNaCs
and HyNaCs—belong to different clades of the DEG/ENaC
family. FaNaCs are activated by the short neuropeptide
FMRFamide, and HyNaCs by Hydra RFamides, which are not
evolutionarily related to FMRFamide. The FMRFamide-binding
site in FaNaCs was recently identified in a cleft atop the
large extracellular domain. However, this cleft is not
conserved in HyNaCs. Here, we combined molecular modeling
and site-directed mutagenesis and identified a putative
binding pocket for Hydra-RFamides in the extracellular
domain of the heterotrimeric HyNaC2/3/5. This pocket
localizes to only one of the three subunit interfaces,
indicating that this trimeric ion channel binds a single
peptide ligand. We engineered an unnatural amino acid at the
putative binding pocket entrance, which allowed covalent
tethering of Hydra RFamide to the channel, thereby trapping
the channel in an open conformation. The identified pocket
localizes to the same region as the acidic pocket of
acid-sensing ion channels (ASICs), which binds peptide
ligands. The pocket in HyNaCs is less acidic, and both
electrostatic and hydrophobic interactions contribute to
peptide binding. Collectively, our results reveal a
conserved ligand-binding pocket in HyNaCs and ASICs and
indicate independent evolution of peptide-binding cavities
in the two subgroups of peptide-gated ion channels.},
cin = {INM-9 / IAS-5},
ddc = {500},
cid = {I:(DE-Juel1)INM-9-20140121 / I:(DE-Juel1)IAS-5-20120330},
pnm = {5252 - Brain Dysfunction and Plasticity (POF4-525)},
pid = {G:(DE-HGF)POF4-5252},
typ = {PUB:(DE-HGF)16},
pubmed = {39365813},
UT = {WOS:001352155400008},
doi = {10.1073/pnas.2409097121},
url = {https://juser.fz-juelich.de/record/1037779},
}