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@ARTICLE{Silva:1037816,
      author       = {Silva, Ingrid F. and Pulignani, Carolina and Odutola,
                      Jokotadeola and Galushchinskiy, Alexey and Teixeira, Ivo F.
                      and Isaacs, Mark and Mesa, Camilo A. and Scoppola, Ernesto
                      and These, Albert and Badamdorj, Bolortuya and Ángel
                      Muñoz-Márquez, Miguel and Zizak, Ivo and Palgrave, Robert
                      and Tarakina, Nadezda V. and Gimenez, Sixto and Brabec,
                      Christoph and Bachmann, Julien and Cortes, Emiliano and
                      Tkachenko, Nikolai and Savateev, Oleksandr and
                      Jiménez-Calvo, Pablo},
      title        = {{E}nhancing deep visible-light photoelectrocatalysis with a
                      single solid-state synthesis: {C}arbon nitride/{T}i{O}2
                      heterointerface},
      journal      = {Journal of colloid and interface science},
      volume       = {678},
      issn         = {0021-9797},
      address      = {Amsterdam [u.a.]},
      publisher    = {Elsevier},
      reportid     = {FZJ-2025-00968},
      pages        = {518 - 533},
      year         = {2025},
      abstract     = {Visible-light responsive, stable, and abundant absorbers
                      are required for the rapid integration of green, clean, and
                      renewable technologies in a circular economy. Photoactive
                      solid–solid heterojunctions enable multiple charge
                      pathways, inhibiting recombination through efficient charge
                      transfer across the interface. This study spotlights the
                      physico-chemical synergy between titanium dioxide (TiO2)
                      anatase and carbon nitride (CN) to form a hybrid material.
                      The $CN(10\%)-TiO2(90\%)$ hybrid outperforms TiO2 and CN
                      references and literature homologs in four photo and
                      photoelectrocatalytic reactions.CN-TiO2 achieved a four-fold
                      increase in benzylamine conversion, with photooxidation
                      conversion rates of 51, 97, and 100 $\%$ at 625, 535, and
                      465 nm, respectively. The associated energy transfer
                      mechanism was elucidated. In photoelectrochemistry, CN-TiO2
                      exhibited 23 $\%$ photoactivity of the full-spectrum
                      measurement when using a 410 nm filter. Our findings
                      demonstrate that CN-TiO2 displayed a band gap of 2.9 eV,
                      evidencing TiO2 photosensitization attributed to enhanced
                      charge transfer at the heterointerface boundaries via
                      staggered heterojunction type II.},
      cin          = {IET-2},
      ddc          = {540},
      cid          = {I:(DE-Juel1)IET-2-20140314},
      pnm          = {1212 - Materials and Interfaces (POF4-121)},
      pid          = {G:(DE-HGF)POF4-1212},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {39260300},
      UT           = {WOS:001312570100001},
      doi          = {10.1016/j.jcis.2024.09.028},
      url          = {https://juser.fz-juelich.de/record/1037816},
}