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| 001 | 1038552 | ||
| 005 | 20250310131248.0 | ||
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| 100 | 1 | _ | |a Stroyuk, Oleksandr |0 P:(DE-Juel1)178670 |b 0 |e Corresponding author |
| 245 | _ | _ | |a Experimental design of (Cs,Rb) 2 Sn(Bi)Cl 6 blue phosphors by cation-substitution-induced lattice strain |
| 260 | _ | _ | |a London [u.a.] |c 2025 |b RSC |
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| 520 | _ | _ | |a A mild high-throughput synthesis of doubly substituted (CsxRb1−x)2SnyBi1−yCl6 perovskites yields single-phase solid-solution compounds in the compositional domain of x = 0–1 and y ≥ 0.75. Bi-substituted compounds emit relatively intense and broadband blue photoluminescence (PL) peaked at 455 nm, originating from the self-trapped excitonic states. Both Sn/Bi and Cs/Rb substitutions were found to exert a lattice strain with the maximal strain magnitudes observed close to x = 0.5 and y = 0.90. The PL parameters of the single-phase (CsxRb1−x)2SnyBi1−yCl6 samples, in particular, the PL intensity and lifetime, as well as the rate constants of radiative and non-radiative recombination, correlate with the strain magnitude. |
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| 773 | _ | _ | |a 10.1039/D4TC03749A |g p. 10.1039.D4TC03749A |0 PERI:(DE-600)2702245-6 |n 5 |p 2303-2311 |t Journal of materials chemistry / C |v 13 |y 2025 |x 2050-7526 |
| 856 | 4 | _ | |u https://juser.fz-juelich.de/record/1038552/files/Sn_LFPs_paper_revision2.pdf |y Published on 2024-12-02. Available in OpenAccess from 2025-12-02. |
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