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@ARTICLE{Adamkiewicz:1039746,
author = {Adamkiewicz, Alexa and Raths, Miriam and Stettner, Monja
and Theilen, Marcel and Münster, Lasse and Wenzel, Sabine
and Hutter, Mark and Soubatch, Serguei and Kumpf, Christian
and Bocquet, Francois C. and Wallauer, Robert and Tautz,
Frank Stefan and Höfer, Ulrich},
title = {{C}oherent and incoherent excitation pathways in
time-resolved photoemission orbital tomography of
{C}u{P}c/{C}u(001)-2{O}},
reportid = {FZJ-2025-01785},
year = {2023},
abstract = {Time-resolved photoemission orbital tomography (tr-POT)
offers unique possibilities for tracing molecular electron
dynamics. The recorded pump-induced changes of the
angle-resolved photoemission intensities allow to
characterize unoccupied molecular states in momentum space
and to deduce the incoherent temporal evolution of their
population. Here, we show for the example of CuPc/Cu(001)-2O
that the method also gives access to the coherent regime and
that different excitation pathways can be disentangled by a
careful analysis of the time-dependent change of the
photoemission momentum pattern. In particular, we
demonstrate by varying photon energy and polarization of the
pump light, how the incoherent temporal evolution of the
LUMO distribution can be distinguished from coherent
contributions of the projected HOMO. Moreover, we report the
selective excitation of molecules with a specific
orientation at normal incidence by aligning the electric
field of the pump light along the molecular axis.},
cin = {PGI-3},
cid = {I:(DE-Juel1)PGI-3-20110106},
pnm = {5213 - Quantum Nanoscience (POF4-521)},
pid = {G:(DE-HGF)POF4-5213},
typ = {PUB:(DE-HGF)25},
url = {https://juser.fz-juelich.de/record/1039746},
}