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001040384 1001_ $$00000-0002-0014-0041$$aCaicedo-Reina, Mauricio$$b0
001040384 245__ $$aComparative Study of Iminodibenzyl and Diphenylamine Derivatives as Hole Transport Materials in Inverted Perovskite Solar Cells
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001040384 520__ $$aPerovskite solar cells (PSCs) have recently achieved over 26 % power conversion efficiency, challenging the dominance of silicon-based alternatives. This progress is significantly driven by innovations in hole transport materials (HTMs), which notably influence the efficiency and stability of PSCs. However, conventional organic HTMs like Spiro-OMeTAD and PTAA, although highly efficient, suffer from thermal degradation, moisture ingress, and high cost. This study explores the potential of iminodibenzyl, a moiety known for its strong electron-donating capabilities in pharmaceutical applications, as a novel HTM. A series of fluorene-based derivatives incorporating iminodibenzyl (TMF-2 and TDF-2) and diphenylamine (TMF-1 and TDF-1) units were synthesized and characterized. The new HTMs demonstrated commendable optical, electrochemical, and thermal properties, as well as enhanced photostability. Among them, TDF-2 achieved a power conversion efficiency (PCE) of 19.38 %, the highest of the new materials. Although these efficiencies are slightly lower than the benchmark PTAA (20.20 %), the study underscores the potential of iminodibenzyl to enhance photostability and increase HOMO levels, making it a promising candidate for future HTM development in PSCs.
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001040384 7001_ $$0P:(DE-Juel1)201567$$aRocha-Ortiz, Juan S.$$b1$$eCorresponding author
001040384 7001_ $$0P:(DE-Juel1)192542$$aWu, Jianchang$$b2
001040384 7001_ $$00000-0001-9992-5449$$aBornschlegl, Andreas J.$$b3
001040384 7001_ $$00000-0002-2757-9417$$aLeon, Salvador$$b4
001040384 7001_ $$00000-0003-1732-1233$$aBarabash, Anastasia$$b5
001040384 7001_ $$00000-0001-7669-7797$$aDario Perea, Jose$$b6
001040384 7001_ $$aWang, Yunuo$$b7
001040384 7001_ $$00000-0001-9797-8280$$aArango-Marín, Vanessa$$b8
001040384 7001_ $$00000-0002-4392-9456$$aOrtiz, Alejandro$$b9
001040384 7001_ $$aLüer, Larry$$b10
001040384 7001_ $$0P:(DE-Juel1)177626$$aHauch, Jens A.$$b11
001040384 7001_ $$aInsuasty, Braulio$$b12
001040384 7001_ $$0P:(DE-Juel1)176427$$aBrabec, Christoph$$b13$$eCorresponding author$$ufzj
001040384 773__ $$0PERI:(DE-600)1478547-X$$a10.1002/chem.202404251$$gp. e202404251$$n13$$pe202404251$$tChemistry - a European journal$$v31$$x0947-6539$$y2025
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