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@ARTICLE{Holmes:1041122,
      author       = {Holmes, Sarah E. and Kondek, Jędrzej and Zhang, Pu and
                      Faka, Vasiliki and Newnham, Jon A. and Gronych, Lara M. and
                      Hansen, Michael Ryan and Zeier, Wolfgang and Cui, Yi},
      title        = {{L}i{I}-{M}odified {G}lass-{C}eramic {L}ithium
                      {T}hioborate: {F}rom {F}undamentals to {A}pplications in
                      {S}olid-{S}tate {B}atteries},
      journal      = {Chemistry of materials},
      volume       = {37},
      number       = {7},
      issn         = {0897-4756},
      address      = {Washington, DC},
      publisher    = {American Chemical Society},
      reportid     = {FZJ-2025-02156},
      pages        = {2642–2649},
      year         = {2025},
      note         = {Supported by funding from the Bundesministerium für
                      Bildung und Forschung (BMBF) for under the FESTBATT cluster
                      of competence (project 03XP0430F)},
      abstract     = {Solid-state batteries are an emerging battery technology
                      rivaling lithium-ion batteries, but before commercialization
                      can occur, new classes of solid-state electrolytes (SSEs)
                      must be investigated to better understand the fundamental
                      properties of these materials and to extend the capabilities
                      of fast charging and cycle life. In this work, we
                      investigate glass-ceramic lithium thioborate (LBS) SSEs with
                      the stoichiometry of $Li_{10}B_{10}S_{20}$ and utilize a
                      rapid synthesis that enables lithium iodide (LiI)
                      modification in $Li_{10}B_{10}S_{20}$. We study the
                      structures of four materials with varying amounts of LiI
                      using X-ray diffraction, pair distribution function, and
                      solid-state NMR and find that LiI breaks down the
                      $B_{10}S_{20}$ supertetrahedra that make up the unit cell of
                      $Li_{10}B_{10}S_{20}$. More LiI increases ionic conductivity
                      by increasing the unit cell volume and the fraction of the
                      glassy phase in the electrolyte. LiI-modified
                      $Li_{10}B_{10}S_{20}$ as an anode-facing SSE enables
                      all-solid-state batteries to cycle well with theoretical
                      capacities up 6.37 $mAh$ $cm^{-2}$ at 0.1C, validating the
                      relevance of LBS SSEs as separators for solid-state
                      batteries.},
      cin          = {IMD-4},
      ddc          = {540},
      cid          = {I:(DE-Juel1)IMD-4-20141217},
      pnm          = {1221 - Fundamentals and Materials (POF4-122)},
      pid          = {G:(DE-HGF)POF4-1221},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:001453766500001},
      doi          = {10.1021/acs.chemmater.5c00224},
      url          = {https://juser.fz-juelich.de/record/1041122},
}