001     1041579
005     20250423202218.0
024 7 _ |a 10.48550/ARXIV.2110.11449
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037 _ _ |a FZJ-2025-02318
100 1 _ |a Martinez-Castro, Jose
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245 _ _ |a Disentangling the Complex Electronic Structure of an Adsorbed Nanographene: Cycloarene C108
260 _ _ |c 2021
|b arXiv
336 7 _ |a Preprint
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520 _ _ |a We combine low-temperature scanning tunneling spectroscopy, CO functionalized tips and algorithmic data analysis to investigate the electronic structure of the molecular cycloarene C108 (graphene nanoring) adsorbed on a Au(111) surface. We demonstrate that CO functionalized tips enhance the visibility of molecular resonances, both in differential conductance spectra and in real-space topographic images without introducing spurious artifacts. Comparing our experimental data with ab-initio density functional theory reveals a remarkably precise agreement of the molecular orbitals and enables us to disentangle close-lying molecular states only separated by 50 meV at an energy of 2 eV below the Fermi level. We propose this combination of techniques as a promising new route for a precise characterization of complex molecules and other physical entities which have electronic resonances in the tip-sample junction.
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650 _ 7 |a Mesoscale and Nanoscale Physics (cond-mat.mes-hall)
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650 _ 7 |a FOS: Physical sciences
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700 1 _ |a Bolat, Rustem
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700 1 _ |a Fan, Qitang
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700 1 _ |a Werner, Simon
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700 1 _ |a Arefi, Hadi
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700 1 _ |a Esat, Taner
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700 1 _ |a Sundermeyer, Jörg
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700 1 _ |a Wagner, Christian
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700 1 _ |a Gottfried, J. Michael
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700 1 _ |a Temirov, Ruslan
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700 1 _ |a Ternes, Markus
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700 1 _ |a Tautz, F. Stefan
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773 _ _ |a 10.48550/ARXIV.2110.11449
856 4 _ |u https://arxiv.org/abs/2110.11449
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