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@ARTICLE{onda:1041586,
author = {Žonda, Martin and Stetsovych, Oleksandr and Korytár,
Richard and Ternes, Markus and Temirov, Ruslan and
Racanelli, Andrea and Tautz, F. Stefan and Jelínek, Pavel
and Novotný, Tomáš and Švec, Martin},
title = {{R}esolving {A}mbiguity of the {K}ondo {T}emperature
{D}etermination in {M}echanically {T}unable
{S}ingle-{M}olecule {K}ondo {S}ystems},
publisher = {arXiv},
reportid = {FZJ-2025-02325},
year = {2018},
abstract = {Determination of the molecular Kondo temperature $T_K$
poses a challenge in most cases when the experimental
temperature cannot be tuned to a sufficient extent. We show
how this ambiguity can be resolved if additional control
parameters are present, such as magnetic field and
mechanical gating. We record the evolution of the
differential conductance by lifting an individual molecule
from the metal surface with the tip of a scanning tunneling
microscope. By fitting the measured conductance spectra with
the single impurity Anderson model we are able to
demonstrate that the lifting tunes the junction continuously
from the strongly correlated Kondo-singlet to the free spin
$1/2$ ground state. In the crossover regime, where $T_K$ is
similar to the temperature of experiment, the fitting yields
ambiguous estimates of $T_K$ varying by an order of
magnitude. We show that analysis of the conductance measured
in two distinct external magnetic fields can be used to
resolve this problem.},
keywords = {Mesoscale and Nanoscale Physics (cond-mat.mes-hall) (Other)
/ FOS: Physical sciences (Other)},
cin = {PGI-3},
cid = {I:(DE-Juel1)PGI-3-20110106},
pnm = {5213 - Quantum Nanoscience (POF4-521)},
pid = {G:(DE-HGF)POF4-5213},
typ = {PUB:(DE-HGF)25},
doi = {10.48550/ARXIV.1811.00351},
url = {https://juser.fz-juelich.de/record/1041586},
}