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@ARTICLE{Taoussi:1041721,
      author       = {Taoussi, S. and Ouaha, A. and Naji, M. and Hoummada, K. and
                      Lahmar, A. and Cailleu, D. and Alami, J. and Manoun, B. and
                      El bouari, A. and Frielinghaus, H. and Bih, L.},
      title        = {{I}nsights into structural, thermal, physical, optical, and
                      electrical properties of novel {Z}n{O}-doped
                      lithium–titanium-phosphate glasses},
      journal      = {Materials chemistry and physics},
      volume       = {334},
      issn         = {0254-0584},
      address      = {New York, NY [u.a.]},
      publisher    = {Elsevier},
      reportid     = {FZJ-2025-02401},
      pages        = {130468},
      year         = {2025},
      abstract     = {This study investigates novel ZnO-doped
                      lithium-titanium-phosphate glasses, synthesized via the
                      melt-quenching method, and characterizes their physical,
                      structural, thermal, optical, chemical, mechanical, and
                      electrical properties, with a focus on the impact of varying
                      ZnO content on these properties. An increase in ZnO content
                      from 20 $mol\%$ to 27.27 $mol\%$ induces significant local
                      structural changes, promoting enhanced network
                      polymerization, density, and chemical durability, while
                      concurrently reducing thermal stability and mechanical
                      strength. EPR analysis confirmed that titanium remained in
                      the Ti4+ state, while optical measurements revealed an
                      increased band gap, attributed to the role of ZnO in
                      preventing Ti4+ reduction and minimizing localized states.
                      The electrical conductivity decreases with increasing ZnO
                      content, with the highest value measured at 1.73 × 10-10
                      Ω-1 cm-1. High-ZnO glasses exhibit mainly electronic
                      conductivity of 4.02 × 10-9 Ω-1 cm-1 at room temperature.
                      The frequency-dependent conductivity follows Jonscher's
                      power law, with the charge transport governed by a
                      correlated barrier-hopping mechanism, remaining stable
                      across temperatures and compositions.},
      cin          = {JCNS-FRM-II / JCNS-4 / MLZ},
      ddc          = {530},
      cid          = {I:(DE-Juel1)JCNS-FRM-II-20110218 /
                      I:(DE-Juel1)JCNS-4-20201012 / I:(DE-588b)4597118-3},
      pnm          = {6G4 - Jülich Centre for Neutron Research (JCNS) (FZJ)
                      (POF4-6G4) / 632 - Materials – Quantum, Complex and
                      Functional Materials (POF4-632)},
      pid          = {G:(DE-HGF)POF4-6G4 / G:(DE-HGF)POF4-632},
      experiment   = {EXP:(DE-MLZ)NOSPEC-20140101},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:001421754000001},
      doi          = {10.1016/j.matchemphys.2025.130468},
      url          = {https://juser.fz-juelich.de/record/1041721},
}