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024 7 _ |a 10.1016/j.matchemphys.2025.130468
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024 7 _ |a 1879-3312
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024 7 _ |a 10.34734/FZJ-2025-02401
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100 1 _ |a Taoussi, S.
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245 _ _ |a Insights into structural, thermal, physical, optical, and electrical properties of novel ZnO-doped lithium–titanium-phosphate glasses
260 _ _ |a New York, NY [u.a.]
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520 _ _ |a This study investigates novel ZnO-doped lithium-titanium-phosphate glasses, synthesized via the melt-quenching method, and characterizes their physical, structural, thermal, optical, chemical, mechanical, and electrical properties, with a focus on the impact of varying ZnO content on these properties. An increase in ZnO content from 20 mol% to 27.27 mol% induces significant local structural changes, promoting enhanced network polymerization, density, and chemical durability, while concurrently reducing thermal stability and mechanical strength. EPR analysis confirmed that titanium remained in the Ti4+ state, while optical measurements revealed an increased band gap, attributed to the role of ZnO in preventing Ti4+ reduction and minimizing localized states. The electrical conductivity decreases with increasing ZnO content, with the highest value measured at 1.73 × 10-10 Ω-1 cm-1. High-ZnO glasses exhibit mainly electronic conductivity of 4.02 × 10-9 Ω-1 cm-1 at room temperature. The frequency-dependent conductivity follows Jonscher's power law, with the charge transport governed by a correlated barrier-hopping mechanism, remaining stable across temperatures and compositions.
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700 1 _ |a Ouaha, A.
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700 1 _ |a Naji, M.
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700 1 _ |a Hoummada, K.
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700 1 _ |a Lahmar, A.
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700 1 _ |a Cailleu, D.
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700 1 _ |a Alami, J.
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700 1 _ |a Manoun, B.
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773 _ _ |a 10.1016/j.matchemphys.2025.130468
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856 4 _ |u https://juser.fz-juelich.de/record/1041721/files/Insights%20into%20Structural%2C%20Thermal%2C%20Physical%2C%20Optical%2C%20and%20Electrical%20Properties%20of%20Novel%20ZnO-Doped%20Lithium-Titanium-Phosphate%20Glasses.pdf
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