Home > Publications database > Insights into structural, thermal, physical, optical, and electrical properties of novel ZnO-doped lithium–titanium-phosphate glasses > print |
001 | 1041721 | ||
005 | 20250804115222.0 | ||
024 | 7 | _ | |a 10.1016/j.matchemphys.2025.130468 |2 doi |
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100 | 1 | _ | |a Taoussi, S. |0 P:(DE-HGF)0 |b 0 |e Corresponding author |
245 | _ | _ | |a Insights into structural, thermal, physical, optical, and electrical properties of novel ZnO-doped lithium–titanium-phosphate glasses |
260 | _ | _ | |a New York, NY [u.a.] |c 2025 |b Elsevier |
336 | 7 | _ | |a article |2 DRIVER |
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520 | _ | _ | |a This study investigates novel ZnO-doped lithium-titanium-phosphate glasses, synthesized via the melt-quenching method, and characterizes their physical, structural, thermal, optical, chemical, mechanical, and electrical properties, with a focus on the impact of varying ZnO content on these properties. An increase in ZnO content from 20 mol% to 27.27 mol% induces significant local structural changes, promoting enhanced network polymerization, density, and chemical durability, while concurrently reducing thermal stability and mechanical strength. EPR analysis confirmed that titanium remained in the Ti4+ state, while optical measurements revealed an increased band gap, attributed to the role of ZnO in preventing Ti4+ reduction and minimizing localized states. The electrical conductivity decreases with increasing ZnO content, with the highest value measured at 1.73 × 10-10 Ω-1 cm-1. High-ZnO glasses exhibit mainly electronic conductivity of 4.02 × 10-9 Ω-1 cm-1 at room temperature. The frequency-dependent conductivity follows Jonscher's power law, with the charge transport governed by a correlated barrier-hopping mechanism, remaining stable across temperatures and compositions. |
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700 | 1 | _ | |a Alami, J. |0 0000-0002-4919-5350 |b 6 |
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773 | _ | _ | |a 10.1016/j.matchemphys.2025.130468 |g Vol. 334, p. 130468 - |0 PERI:(DE-600)1491959-X |p 130468 |t Materials chemistry and physics |v 334 |y 2025 |x 0254-0584 |
856 | 4 | _ | |u https://juser.fz-juelich.de/record/1041721/files/Insights%20into%20Structural%2C%20Thermal%2C%20Physical%2C%20Optical%2C%20and%20Electrical%20Properties%20of%20Novel%20ZnO-Doped%20Lithium-Titanium-Phosphate%20Glasses.pdf |y Published on 2025-01-31. Available in OpenAccess from 2027-01-31. |
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