| Hauptseite > Publikationsdatenbank > Investigation of Me-TDDGA as Extractant for Grouped Actinides Separation from Lanthanides > print |
| 001 | 1042713 | ||
| 005 | 20250717202249.0 | ||
| 024 | 7 | _ | |a 10.34734/FZJ-2025-02659 |2 datacite_doi |
| 037 | _ | _ | |a FZJ-2025-02659 |
| 041 | _ | _ | |a English |
| 100 | 1 | _ | |a Benhajjam, Zineb |0 P:(DE-Juel1)206850 |b 0 |u fzj |
| 245 | _ | _ | |a Investigation of Me-TDDGA as Extractant for Grouped Actinides Separation from Lanthanides |f - 2025-05-23 |
| 260 | _ | _ | |c 2025 |
| 300 | _ | _ | |a 66 p. |
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| 336 | 7 | _ | |a Thesis |0 2 |2 EndNote |
| 336 | 7 | _ | |a MASTERSTHESIS |2 BibTeX |
| 336 | 7 | _ | |a masterThesis |2 DRIVER |
| 336 | 7 | _ | |a Master Thesis |b master |m master |0 PUB:(DE-HGF)19 |s 1752496922_7152 |2 PUB:(DE-HGF) |
| 336 | 7 | _ | |a SUPERVISED_STUDENT_PUBLICATION |2 ORCID |
| 502 | _ | _ | |a Masterarbeit, University of Applied Sciences Aachen, 2025 |c University of Applied Sciences Aachen |b Masterarbeit |d 2025 |o 2025-05-23 |
| 520 | _ | _ | |a The removal of minor actinides (MAs) from nuclear waste - in particular the separation of Am(III) from lanthanide (Ln) fission products - is an important step in the partitioning and transmutation (P&T) strategy aimed at reducing long-term heat load and radiotoxicity. In this study, a newly synthesized DGA ligand, 2-(2-[didecyl]-2-oxoethoxy)-N,N-didecylpropanamide (Me-TDDGA), was evaluated for its extraction performance and selectivity towards tri- and tetravalent actinides and trivalent lanthanides under different experimental conditions. While Me-TDDGA alone did not achieve significant separation between An(III) and Ln(III), the introduction of 2,6-bis(5,6-di(sulfophenyl)-1,2,4-triazin-3-yl)pyridine (SO₃-Ph-BTP) as a co-extractant showed remarkable improvements in separation factors. Additionally, the use of 2,6-bis[1-(propan-1-ol)-1,2,3-triazol-4-yl)]pyridine (PTD), a better alternative to SO3-Ph-BTP as it obeys the CHON principle, was investigated, and higher concentrations can further improve selectivity. These results highlight the potential of multi-component extraction systems and set the stage for future optimization towards more efficient actinide-lanthanide separations. |
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