% IMPORTANT: The following is UTF-8 encoded. This means that in the presence
% of non-ASCII characters, it will not work with BibTeX 0.99 or older.
% Instead, you should use an up-to-date BibTeX implementation like “bibtex8” or
% “biber”.
@ARTICLE{McKenzie:1043160,
author = {McKenzie, Iain and DiPasquale, Mitchell and Dziura,
Maksymilian and Gutberlet, Thomas and Hartwig, Nathan A. and
Karner, Victoria L. and Scheuermann, Robert and Marquardt,
Drew},
title = {{N}anoscale dynamics in model phospholipid biomembranes
probed by muon spin resonance spectroscopy: {T}he effects of
membrane composition and temperature on acyl chain and
cholesterol motion},
journal = {Chemistry and physics of lipids},
volume = {270},
issn = {0009-3084},
address = {Amsterdam [u.a.]},
publisher = {Elsevier Science},
reportid = {FZJ-2025-02776},
pages = {105496 -},
year = {2025},
abstract = {The physical properties of lipid bilayers are known to
depend on their composition, but there has recently been
controversy about whether cholesterol (chol) does or does
not stiffen biomembranes containing unsaturated
phospholipids. Herein, avoided level crossing muon spin
resonance (ALC-𝜇SR) spectroscopy has been used to probe
the local dynamics in model biomembranes composed of the
saturated phospholipid
1,2-dipalmitoyl-sn-glycero-3-phosphocholine (DPPC), the
unsaturated phospholipids
1-palmitoyl-2-oleoyl-glycero-3-phosphocholine (POPC) and
1,2-dioleoyl-sn-glycero-3-phosphocholine (DOPC), and the
sterol chol. The presence of chol significantly stiffens the
acyl chains in lipid mixtures as evident from the reduction
of the amplitude of restricted reorientational motion in the
acyl chain at the C9-C10 position and the increase of the
torsional barrier for rotation about the bonds in the acyl
chain. Swapping POPC for DOPC slightly increases the
amplitude of restricted reorientational motion and decreases
the torsional barrier of the acyl chains, but the magnitude
of the effect is much smaller than the inclusion of chol.},
cin = {JCNS-2 / JCNS-HBS / JARA-FIT},
ddc = {530},
cid = {I:(DE-Juel1)JCNS-2-20110106 / I:(DE-Juel1)JCNS-HBS-20180709
/ $I:(DE-82)080009_20140620$},
pnm = {632 - Materials – Quantum, Complex and Functional
Materials (POF4-632) / 6G4 - Jülich Centre for Neutron
Research (JCNS) (FZJ) (POF4-6G4)},
pid = {G:(DE-HGF)POF4-632 / G:(DE-HGF)POF4-6G4},
experiment = {EXP:(DE-MLZ)NOSPEC-20140101},
typ = {PUB:(DE-HGF)16},
pubmed = {40451379},
UT = {WOS:001508527500001},
doi = {10.1016/j.chemphyslip.2025.105496},
url = {https://juser.fz-juelich.de/record/1043160},
}