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@ARTICLE{Eberst:1043283,
author = {Eberst, Alexander and Xu, Binbin and Bittkau, Karsten and
Lambertz, Andreas and Rau, Uwe and Ding, Kaining},
title = {{P}erformance improvements through gradient layers in
transparent passivating contact solar cells},
journal = {Cell reports / Physical science},
volume = {6},
issn = {2666-3864},
address = {Maryland Heights, MO},
publisher = {Cell Press},
reportid = {FZJ-2025-02809},
pages = {102658},
year = {2025},
abstract = {Transparent passivating contact solar cells using
hydrogenated n-type nanocrystalline silicon carbide
(nc-SiC:H(n)) utilize a double-layer stack consisting of one
passivation-optimized and one conduction-optimized
nc-SiC:H(n) layer. This double-layer configuration limits
the fill factor (FF) due to the passivating layer’s low
electrical conductivity. This study enhances this structure
by introducing a gradient layer that transitions from
passivating-like to conducting-like properties. While
replacing the passivating layer alone does not improve
performance, when combining it with an ultrathin passivating
seed layer, the gradient layer effectively balances voltage
and FF trade-offs. This results in higher device voltage and
FF. Microstructural analysis shows hydrogen content near the
crystalline Si interface similar to the double-layer
approach but with increased electrical conductivity earlier
in the layer stack. These improvements boost both FF and
open-circuit voltage by $0.6\%$ absolute and over 4 mV,
respectively.},
cin = {IMD-3},
ddc = {530},
cid = {I:(DE-Juel1)IMD-3-20101013},
pnm = {1212 - Materials and Interfaces (POF4-121)},
pid = {G:(DE-HGF)POF4-1212},
typ = {PUB:(DE-HGF)16},
UT = {WOS:001540265100001},
doi = {10.1016/j.xcrp.2025.102658},
url = {https://juser.fz-juelich.de/record/1043283},
}