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| Hauptseite > Publikationsdatenbank > Assessing the Impact of $Li^+$ Concentration and Stacking Faults in the Aliovalent-Substituted Ionic Conductor $Li_3ScCl_6$ > print |
| Hauptseite > Publikationsdatenbank > Assessing the Impact of $Li^+$ Concentration and Stacking Faults in the Aliovalent-Substituted Ionic Conductor $Li_3ScCl_6$ > print |
| 001 | 1043534 | ||
| 005 | 20251027132718.0 | ||
| 024 | 7 | _ | |a 10.1021/acs.inorgchem.5c01371 |2 doi |
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| 037 | _ | _ | |a FZJ-2025-02910 |
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| 100 | 1 | _ | |a Rosenbach, Carolin |0 P:(DE-HGF)0 |b 0 |
| 245 | _ | _ | |a Assessing the Impact of $Li^+$ Concentration and Stacking Faults in the Aliovalent-Substituted Ionic Conductor $Li_3ScCl_6$ |
| 260 | _ | _ | |a Washington, DC |c 2025 |b American Chemical Society |
| 336 | 7 | _ | |a article |2 DRIVER |
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| 520 | _ | _ | |a Halide electrolytes have gained interest due to their decent conductivities in the $mS·cm^{–1}$ range and wide electrochemical stability windows. The ionic transport can be influenced by changing the $Li^+$ concentration in the structure. Due to the high cost of the rare-earth elements in the halide electrolytes, the substitution of lower-cost elements is favored. Based on the idea of changing the $Li^+$ concentration and substituting with low-cost elements, the two substitution series $Li_{3–x}Sc_{1–x}Zr_xCl_6$ and $Li_{3–x}Sc_{1–x}Mg_xCl_6$ (0 ≤ $x$ ≤ 0.3) are investigated in this work. Structural information was obtained by X-ray and neutron diffraction and combined with transport properties obtained by impedance spectroscopy. Two main transport influencing factors were found: The $Li^+$ concentration and the c/a lattice parameter. The occupation of the $Li^+$-only layers seems to affect the lattice parameter in the c-direction. However, the structural refinement was not straightforward as stacking faults appear in layered halide materials that complicate the refinements, and the substitution with $Mg^{2+}$ seems to influence the extent of stacking fault formation. Overall, this work highlights the need to consider several factors in halide materials to correlate the structure–transport processes. |
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| 700 | 1 | _ | |a Helm, Bianca |0 P:(DE-HGF)0 |b 1 |
| 700 | 1 | _ | |a Suard, Emmanuelle |0 0000-0001-5966-5929 |b 2 |
| 700 | 1 | _ | |a Lotsch, Bettina V. |0 0000-0002-3094-303X |b 3 |
| 700 | 1 | _ | |a Bette, Sebastian |0 0000-0003-3575-0517 |b 4 |
| 700 | 1 | _ | |a Zeier, Wolfgang G. |0 P:(DE-Juel1)184735 |b 5 |e Corresponding author |
| 773 | _ | _ | |a 10.1021/acs.inorgchem.5c01371 |g p. acs.inorgchem.5c01371 |0 PERI:(DE-600)1484438-2 |n 25 |p 12698-12707 |t Inorganic chemistry |v 64 |y 2025 |x 0020-1669 |
| 856 | 4 | _ | |u https://juser.fz-juelich.de/record/1043534/files/revised_manuscript.pdf |y Published on 2025-06-12. Available in OpenAccess from 2026-06-12. |
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