001044611 001__ 1044611
001044611 005__ 20250804115246.0
001044611 0247_ $$2doi$$a10.1002/anie.202424515
001044611 0247_ $$2ISSN$$a1433-7851
001044611 0247_ $$2ISSN$$a0570-0833
001044611 0247_ $$2ISSN$$a1521-3773
001044611 0247_ $$2datacite_doi$$a10.34734/FZJ-2025-03282
001044611 0247_ $$2pmid$$a40127212
001044611 0247_ $$2WOS$$aWOS:001457461700001
001044611 037__ $$aFZJ-2025-03282
001044611 082__ $$a540
001044611 1001_ $$0P:(DE-Juel1)192542$$aWu, Jianchang$$b0$$eCorresponding author
001044611 245__ $$aHighly Stable Sn─Pb Perovskite Solar Cells Enabled by Phenol‐Functionalized Hole Transporting Material
001044611 260__ $$aWeinheim$$bWiley-VCH$$c2025
001044611 3367_ $$2DRIVER$$aarticle
001044611 3367_ $$2DataCite$$aOutput Types/Journal article
001044611 3367_ $$0PUB:(DE-HGF)16$$2PUB:(DE-HGF)$$aJournal Article$$bjournal$$mjournal$$s1753771537_3184
001044611 3367_ $$2BibTeX$$aARTICLE
001044611 3367_ $$2ORCID$$aJOURNAL_ARTICLE
001044611 3367_ $$00$$2EndNote$$aJournal Article
001044611 520__ $$aSn─Pb perovskites, a most promising low bandgap semiconductor for multi-junction solar cells, are often limited by instability due to the susceptibility of Sn2+ to oxidation. Inspired by the antioxidative properties of polyphenolic compounds, we introduce the reductive phenol group and strong electronegative fluorine into an organic conjugated structure and design a multi-functional polymer with fluorine and phenol units (PF─OH). The design of PF─OH allows the effective rise in the energy barrier of Sn2+ oxidation, leading to a significant enhancement in the stability of Sn─Pb perovskite devices from 200 to 8000 h—an improvement of around 100 times. Additionally, the strong binding energy between Sn2+ and the phenol in PF─OH critically influences Sn─Pb perovskite's crystallization and grain growth, resulting in perovskite films with fewer pinholes at the buried interface and extended carrier lifetimes. This enhancement not only boosts the power conversion efficiency (PCE) to 23.61%, but also significantly improves the operational stability of the devices. Ultimately, this design strategy has been proven universal through the phenolization of a series of molecules, marking a milestone in enhancing the stability of Sn─Pb perovskites.
001044611 536__ $$0G:(DE-HGF)POF4-1213$$a1213 - Cell Design and Development (POF4-121)$$cPOF4-121$$fPOF IV$$x0
001044611 588__ $$aDataset connected to CrossRef, Journals: juser.fz-juelich.de
001044611 7001_ $$0P:(DE-Juel1)207942$$aHu, Manman$$b1$$ufzj
001044611 7001_ $$0P:(DE-HGF)0$$aDai, Qingqing$$b2
001044611 7001_ $$0P:(DE-HGF)0$$aAlkan, Ecem Aydan$$b3
001044611 7001_ $$0P:(DE-HGF)0$$aBarabash, Anastasia$$b4
001044611 7001_ $$0P:(DE-Juel1)194716$$aZhang, Jiyun$$b5
001044611 7001_ $$0P:(DE-Juel1)201377$$aLiu, Chao$$b6
001044611 7001_ $$0P:(DE-Juel1)177626$$aHauch, Jens$$b7
001044611 7001_ $$aHan, Gao-Feng$$b8
001044611 7001_ $$aJiang, Qing$$b9
001044611 7001_ $$0P:(DE-HGF)0$$aWang, Tonghui$$b10$$eCorresponding author
001044611 7001_ $$0P:(DE-HGF)0$$aSeok, Sang Il$$b11$$eCorresponding author
001044611 7001_ $$0P:(DE-Juel1)176427$$aBrabec, Christoph$$b12$$eCorresponding author
001044611 773__ $$0PERI:(DE-600)2011836-3$$a10.1002/anie.202424515$$gVol. 64, no. 22, p. e202424515$$n22$$pe202424515$$tAngewandte Chemie / International edition$$v64$$x1433-7851$$y2025
001044611 8564_ $$uhttps://juser.fz-juelich.de/record/1044611/files/Angew%20Chem%20Int%20Ed%20-%202025%20-%20Wu%20-%20Highly%20Stable%20Sn%20Pb%20Perovskite%20Solar%20Cells%20Enabled%20by%20Phenol%E2%80%90Functionalized%20Hole-1.pdf$$yOpenAccess
001044611 909CO $$ooai:juser.fz-juelich.de:1044611$$pdnbdelivery$$pdriver$$pVDB$$popen_access$$popenaire
001044611 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)192542$$aForschungszentrum Jülich$$b0$$kFZJ
001044611 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)207942$$aForschungszentrum Jülich$$b1$$kFZJ
001044611 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-HGF)0$$aForschungszentrum Jülich$$b3$$kFZJ
001044611 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)194716$$aForschungszentrum Jülich$$b5$$kFZJ
001044611 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)201377$$aForschungszentrum Jülich$$b6$$kFZJ
001044611 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)177626$$aForschungszentrum Jülich$$b7$$kFZJ
001044611 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)176427$$aForschungszentrum Jülich$$b12$$kFZJ
001044611 9131_ $$0G:(DE-HGF)POF4-121$$1G:(DE-HGF)POF4-120$$2G:(DE-HGF)POF4-100$$3G:(DE-HGF)POF4$$4G:(DE-HGF)POF$$9G:(DE-HGF)POF4-1213$$aDE-HGF$$bForschungsbereich Energie$$lMaterialien und Technologien für die Energiewende (MTET)$$vPhotovoltaik und Windenergie$$x0
001044611 9141_ $$y2025
001044611 915__ $$0StatID:(DE-HGF)0200$$2StatID$$aDBCoverage$$bSCOPUS$$d2024-12-16
001044611 915__ $$0StatID:(DE-HGF)0160$$2StatID$$aDBCoverage$$bEssential Science Indicators$$d2024-12-16
001044611 915__ $$0LIC:(DE-HGF)CCBY4$$2HGFVOC$$aCreative Commons Attribution CC BY 4.0
001044611 915__ $$0StatID:(DE-HGF)0600$$2StatID$$aDBCoverage$$bEbsco Academic Search$$d2024-12-16
001044611 915__ $$0StatID:(DE-HGF)9915$$2StatID$$aIF >= 15$$bANGEW CHEM INT EDIT : 2022$$d2024-12-16
001044611 915__ $$0StatID:(DE-HGF)1150$$2StatID$$aDBCoverage$$bCurrent Contents - Physical, Chemical and Earth Sciences$$d2024-12-16
001044611 915__ $$0StatID:(DE-HGF)3001$$2StatID$$aDEAL Wiley$$d2024-12-16$$wger
001044611 915__ $$0StatID:(DE-HGF)1030$$2StatID$$aDBCoverage$$bCurrent Contents - Life Sciences$$d2024-12-16
001044611 915__ $$0StatID:(DE-HGF)1210$$2StatID$$aDBCoverage$$bIndex Chemicus$$d2024-12-16
001044611 915__ $$0StatID:(DE-HGF)0113$$2StatID$$aWoS$$bScience Citation Index Expanded$$d2024-12-16
001044611 915__ $$0StatID:(DE-HGF)0150$$2StatID$$aDBCoverage$$bWeb of Science Core Collection$$d2024-12-16
001044611 915__ $$0StatID:(DE-HGF)0510$$2StatID$$aOpenAccess
001044611 915__ $$0StatID:(DE-HGF)0030$$2StatID$$aPeer Review$$bASC$$d2024-12-16
001044611 915__ $$0StatID:(DE-HGF)1200$$2StatID$$aDBCoverage$$bChemical Reactions$$d2024-12-16
001044611 915__ $$0StatID:(DE-HGF)0100$$2StatID$$aJCR$$bANGEW CHEM INT EDIT : 2022$$d2024-12-16
001044611 915__ $$0StatID:(DE-HGF)0300$$2StatID$$aDBCoverage$$bMedline$$d2024-12-16
001044611 915__ $$0StatID:(DE-HGF)0420$$2StatID$$aNationallizenz$$d2024-12-16$$wger
001044611 915__ $$0StatID:(DE-HGF)0199$$2StatID$$aDBCoverage$$bClarivate Analytics Master Journal List$$d2024-12-16
001044611 920__ $$lyes
001044611 9201_ $$0I:(DE-Juel1)IET-2-20140314$$kIET-2$$lHelmholtz-Institut Erlangen-Nürnberg Erneuerbare Energien$$x0
001044611 980__ $$ajournal
001044611 980__ $$aVDB
001044611 980__ $$aUNRESTRICTED
001044611 980__ $$aI:(DE-Juel1)IET-2-20140314
001044611 9801_ $$aFullTexts