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@ARTICLE{Gebrewold:1044645,
author = {Gebrewold, Habtamu Tsegaye and Bittkau, Karsten and
Lambertz, Andreas and Rau, Uwe and Ding, Kaining},
title = {{D}etailed {B}ias‐{D}ependent {F}ree {E}nergy {L}oss
{A}nalysis for {P}roposing {D}evice {O}ptimization
{S}trategies in {S}ilicon {H}eterojunction {S}olar {C}ell
{D}esign},
journal = {Solar RRL},
volume = {9},
number = {15},
issn = {2367-198X},
address = {Weinheim},
publisher = {Wiley-VCH},
reportid = {FZJ-2025-03309},
pages = {202500311},
year = {2025},
abstract = {A multiscale electro-optical device model is employed to
investigate free energy and other losses in a silicon
heterojunction (SHJ) solar cell. A finite element
method-based device model is coupled with free energy loss
analysis (FELA) to calculate detailed bias voltage-dependent
losses in terms of mAcm-2 and mWcm-2. Such an approach
provides insight into identifying possible pathways for
synergetic optimization and redesigning a solar cell device
in both laboratory and mass production settings. The SHJ
solar cell investigated in this work demonstrates that the
hole-selective contact (HSC) is responsible for a
significant portion of the free energy loss. At maximum
power point, a power density of ~1.6 mWcm-2 at 1 sun is lost
associated with carrier transport in HSC and recombination
at both selective contacts. This results in a $1.6\%$
absolute loss in power conversion efficiency (PCE). Auger
recombination in the wafer limits the open-circuit voltage.
The FELA suggests a pathway for synergistic optimization of
the device to regain a significant portion of the $~2.6\%$
absolute loss in PCE. Simultaneously adjusting the
conductivity of a-Si layers in HSC and the concentration of
free majority carriers in the wafer can improve the fill
factor (FF) to $~87\%$ and PCE close to $26\%.$},
cin = {IMD-3},
ddc = {600},
cid = {I:(DE-Juel1)IMD-3-20101013},
pnm = {1215 - Simulations, Theory, Optics, and Analytics (STOA)
(POF4-121)},
pid = {G:(DE-HGF)POF4-1215},
typ = {PUB:(DE-HGF)16},
doi = {10.1002/solr.202500311},
url = {https://juser.fz-juelich.de/record/1044645},
}