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@ARTICLE{Saboor:1044675,
author = {Saboor, Abdus and Stroyuk, Oleksandr and Raievska,
Oleksandra and Liu, Chao and Hauch, Jens and Brabec,
Christoph},
title = {{Z}n{O} quantum dots as an electron-transport layer for
highly efficient and stable organic solar cells},
journal = {Nanoscale},
volume = {17},
number = {28},
issn = {2040-3364},
address = {Cambridge},
publisher = {RSC Publ.},
reportid = {FZJ-2025-03324},
pages = {16873 - 16881},
year = {2025},
abstract = {An advanced protocol for the mild synthesis of stable and
concentrated ZnO quantum dots (QDs) yields colloidal inks
suitable for applications in electron-transport layers
(ETLs) of organic solar cells, delivering superior power
conversion efficiency (PCE) and photodegradation stability
as compared to bulk-like commercially available ZnO inks.
The champion ZnO QDs-based devices with a quaternary
PM6 : L8BO : BTP-eC9 : PC70BM absorber exhibit a
PCE of $18.86\%,$ surpassing similar cells with bulk-like
ZnO ETL $(18.15\%).$ The ZnO QDs exhibited size-dependent
electron-transport efficiency, with the highest performance
achieved for QDs of 4.4–4.5 nm, decreasing for larger QDs
down to the level of the bulk-like ZnO reference. A
correlation between the photoluminescence and
electron-transport efficiencies of ZnO quantum dots (QDs)
was observed and interpreted in terms of an interplay
between the defect state density and exciton confinement in
size-selected ZnO QDs.},
cin = {IET-2},
ddc = {600},
cid = {I:(DE-Juel1)IET-2-20140314},
pnm = {1213 - Cell Design and Development (POF4-121)},
pid = {G:(DE-HGF)POF4-1213},
typ = {PUB:(DE-HGF)16},
pubmed = {40613427},
UT = {WOS:001522507300001},
doi = {10.1039/D5NR01722J},
url = {https://juser.fz-juelich.de/record/1044675},
}