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@INPROCEEDINGS{SchulzeKppers:1046016,
author = {Schulze-Küppers, Falk and Gross-Barsnick, Sonja-Michaela
and Liang, Shengzhi and Baumann, Stefan and Meulenberg,
Wilhelm Albert and Hall, Christopher and Margaritis,
Nikolaos},
title = {{I}nsights from module autopsy and post-test analysis of
{J}ülich’s first {O}xygen transport membrane reactor
module},
reportid = {FZJ-2025-03656},
year = {2025},
abstract = {High-temperature membrane reactors employing mixed ionic
electronic conducting (MIEC) membranes represent a promising
approach for gas separation and many chemical synthesis
routes which use thermal energy only instead of
electricity.Oxygen transport membranes made of Fe-doped
SrTiO₃ are a key component of these modules. This material
was selected because of its favourable thermochemical
properties and high oxygen permeation. The integration of
the membranes into metallic reactors necessitate the precise
alignment of the thermal expansion and chemical
compatibility between all components. Sealants based on
barium-calcium-silicate-glasses have proven to be a viable
solution for joining and sealing, enabling gas-tight bonds
between the membrane and metal, as well as between the metal
components.The post-test investigation of the first Jülich
membrane modules after their operational deployment provided
comprehensive insights into the degradation processes that
occur within the modules during their operational lifetime.
This talk introduces the methodology of a membrane module
autopsy and demonstrates the dismantling of a module for
subsequent post-test analysis. Changes in the module
components due to contact with corrosive gases at high
temperatures will be shown. The results provide a basis for
improving the durability and performance of membrane modules
by optimizing material combinations, joining techniques, and
module designs.},
month = {Aug},
date = {2025-08-31},
organization = {19. Conference of the European Ceramic
Society, Dresden (Germany), 31 Aug 2025
- 5 Sep 2025},
subtyp = {After Call},
cin = {ITE / IET-1 / IMD-2},
cid = {I:(DE-Juel1)ITE-20250108 / I:(DE-Juel1)IET-1-20110218 /
I:(DE-Juel1)IMD-2-20101013},
pnm = {1232 - Power-based Fuels and Chemicals (POF4-123)},
pid = {G:(DE-HGF)POF4-1232},
typ = {PUB:(DE-HGF)6},
url = {https://juser.fz-juelich.de/record/1046016},
}