001046550 001__ 1046550
001046550 005__ 20250930202057.0
001046550 037__ $$aFZJ-2025-03860
001046550 1001_ $$0P:(DE-Juel1)194360$$aHensen, Laurin$$b0$$eCorresponding author
001046550 1112_ $$a76th Annual Meeting of the International Society of Electrochemistry$$cMainz$$d2025-09-07 - 2025-09-12$$wGermany
001046550 245__ $$aMeasuring hydrogen diffusion, solubility, and permeability of polymers
001046550 260__ $$c2025
001046550 3367_ $$033$$2EndNote$$aConference Paper
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001046550 520__ $$aThe rise of the hydrogen economy requires new materials for the storage, separation and transportation of hydrogen. Hereto, polymers display an outstanding role due to their unique properties, including mechanical strength, thermal stability and chemical resistance, while their permeability to hydrogen is relevant for their applicability. However, literature data on the hydrogen permeability (which is determined by the product of solubility and diffusion) of polymers are rare. To measure these physical properties, this study advanced the electrochemical measurement of the hydrogen transport dynamics and combines this high-quality experimental data with fits of Fick's second law to describe transient pressure variations. This technique is applied to polyether ether ketone (PEEK), polypropylene (PP), polyphenylene sulfide (PPS), and Polytetrafluoroethylene (PTFE) within a temperature range of 30–80 °C. In the permeation cell designed to measure hydrogen permeation, the polymer is coated with a sputtered palladium layer, while hydrogen is detected via electrochemical oxidation. To measure the hydrogen permeation dynamics, the applied hydrogen pressure is reduced instantly to atmospheric pressure at time = 0s. Thus, the permeation current switches from one equilibrium to another, while the dynamics of the transition between these states is used to determine the diffusion coefficient and the solubility of hydrogen. The determined diffusion coefficients and solubilities are analyzed as a function of temperature to determine activation energies and enthalpies of solution.
001046550 536__ $$0G:(DE-HGF)POF4-1231$$a1231 - Electrochemistry for Hydrogen (POF4-123)$$cPOF4-123$$fPOF IV$$x0
001046550 536__ $$0G:(DE-Juel1)BMBF-03SF0627A$$aiNEW2.0 - Verbundvorhaben iNEW2.0: Im Zentrum des Inkubators Nachhaltige Elektrochemische Wertschöpfungsketten (iNEW 2.0) steht die Erforschung und Entwicklung neuartiger und leistungsfähiger Elektrolyse-verfahren zur Anwendung in nachhaltigen Power-to-X (P2X) Wertschöpfungsketten. (BMBF-03SF0627A)$$cBMBF-03SF0627A$$x1
001046550 536__ $$0G:(DE-Juel1)HITEC-20170406$$aHITEC - Helmholtz Interdisciplinary Doctoral Training in Energy and Climate Research (HITEC) (HITEC-20170406)$$cHITEC-20170406$$x2
001046550 7001_ $$0P:(DE-Juel1)179453$$aSchalenbach, Maximilian$$b1
001046550 7001_ $$0P:(DE-Juel1)161208$$aTempel, Hermann$$b2
001046550 7001_ $$0P:(DE-Juel1)156123$$aEichel, Rüdiger-A.$$b3
001046550 909CO $$ooai:juser.fz-juelich.de:1046550$$pVDB
001046550 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)194360$$aForschungszentrum Jülich$$b0$$kFZJ
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001046550 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)179453$$aForschungszentrum Jülich$$b1$$kFZJ
001046550 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)161208$$aForschungszentrum Jülich$$b2$$kFZJ
001046550 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)156123$$aForschungszentrum Jülich$$b3$$kFZJ
001046550 9101_ $$0I:(DE-588b)36225-6$$6P:(DE-Juel1)156123$$aRWTH Aachen$$b3$$kRWTH
001046550 9131_ $$0G:(DE-HGF)POF4-123$$1G:(DE-HGF)POF4-120$$2G:(DE-HGF)POF4-100$$3G:(DE-HGF)POF4$$4G:(DE-HGF)POF$$9G:(DE-HGF)POF4-1231$$aDE-HGF$$bForschungsbereich Energie$$lMaterialien und Technologien für die Energiewende (MTET)$$vChemische Energieträger$$x0
001046550 9141_ $$y2025
001046550 920__ $$lyes
001046550 9201_ $$0I:(DE-Juel1)IET-1-20110218$$kIET-1$$lGrundlagen der Elektrochemie$$x0
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