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100 1 _ |a Heuer, Philip
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245 _ _ |a Attaining a fast-conducting, hybrid solid state separator for all solid-state batteries through a facile wet infiltration method
260 _ _ |a Beijing
|c 2025
|b Royal Society of Chemistry
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520 _ _ |a Thin, fast-conducting and mechanically robust separators are expected to be advantageous in enabling all-solid-state batteries with high energy densities and good electrochemical performance. In this study, a potentially new scalable fabrication route for flexible thiophosphate–polymer separator membranes is demonstrated. By infiltrating a commercially available polymer mesh with the highly conductive inorganic solid ion conductor $Li_{5.5}PS_{4.5}Cl_{1.5}$, a hybrid separator membrane with a high ionic conductivity is realized. The electrochemical evaluation via rate capability tests reveals superior performance at low stack pressures and high C-rates, when comparing cells employing the hybrid membrane separator, to cells utilizing conventional solid electrolyte separators. As a proof of concept, a full cell implementing the hybrid membrane between a Si-based anode and a $LiNi_{0.83}Co_{0.11}Mn_{0.06}O_2–Li_{5.5}PS_{4.5}Cl_{1.5}$ composite cathode is evaluated. The experimental work is complemented by resistor network modelling of the hybrid membrane sheets, shedding light on potential challenges in cell operation.
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700 1 _ |a Ketter, Lukas
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700 1 _ |a Rana, Moumita
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700 1 _ |a Scharf, Felix
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700 1 _ |a Brunklaus, Gunther
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700 1 _ |a Zeier, Wolfgang
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773 _ _ |a 10.1039/D5YA00141B
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|t Energy advances
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856 4 _ |u https://juser.fz-juelich.de/record/1047019/files/d5ya00141b.pdf
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