Gast ::
| Hauptseite > Publikationsdatenbank > Impact of structural coherence and disorder on the ionic transport and lattice dynamics in $Li^+$ -conducting argyrodites > print |
| Hauptseite > Publikationsdatenbank > Impact of structural coherence and disorder on the ionic transport and lattice dynamics in $Li^+$ -conducting argyrodites > print |
| 001 | 1047538 | ||
| 005 | 20260122125259.0 | ||
| 024 | 7 | _ | |a 10.1039/D5TA07185B |2 doi |
| 024 | 7 | _ | |a 2050-7488 |2 ISSN |
| 024 | 7 | _ | |a 2050-7496 |2 ISSN |
| 024 | 7 | _ | |a 10.34734/FZJ-2025-04368 |2 datacite_doi |
| 024 | 7 | _ | |a 41132693 |2 pmid |
| 024 | 7 | _ | |a WOS:001599319000001 |2 WOS |
| 037 | _ | _ | |a FZJ-2025-04368 |
| 082 | _ | _ | |a 530 |
| 100 | 1 | _ | |a Böger, Thorben |0 P:(DE-HGF)0 |b 0 |
| 245 | _ | _ | |a Impact of structural coherence and disorder on the ionic transport and lattice dynamics in $Li^+$ -conducting argyrodites |
| 260 | _ | _ | |a London [u.a.] |c 2025 |b RSC |
| 336 | 7 | _ | |a article |2 DRIVER |
| 336 | 7 | _ | |a Output Types/Journal article |2 DataCite |
| 336 | 7 | _ | |a Journal Article |b journal |m journal |0 PUB:(DE-HGF)16 |s 1768303241_952 |2 PUB:(DE-HGF) |
| 336 | 7 | _ | |a ARTICLE |2 BibTeX |
| 336 | 7 | _ | |a JOURNAL_ARTICLE |2 ORCID |
| 336 | 7 | _ | |a Journal Article |0 0 |2 EndNote |
| 520 | _ | _ | |a Solid-state batteries offer improved safety and higher energy density compared to conventional lithium-ion systems. Among candidate solid electrolytes, lithium argyrodites stand out for their exceptional ionic conductivity and compositional flexibility. Recent studies have revealed strongly anharmonic, liquid-like ion and lattice dynamics in these materials, including the collapse of soft phonons driven by $Li^+ $diffusion, which impacts both local vibrations and thermal transport. Yet, the connection between the local structure, phonon dynamics, and macroscopic heat transport remains unresolved. In this work, we employ post-synthesis processing to tune microstructural parameters—such as crystallite size, strain, and coherence length—in two model systems: $Li_{5.5}PS_{4.5}Cl_{1.5}$ and $Li_6PS_5Br$. We systematically examine how mechanical treatments influence structural coherence, ion and lattice dynamics, and thermal transport. To further probe the role of structural disorder, we investigate bromide substitution in $Li_6PS_5I$. Across all compounds, thermal transport above 100 K is dominated by diffusons. At lower temperatures, however, structural disorder is significantly more effective than reduced coherence length at suppressing phonon-gas-type transport, underscoring the crucial role of the local structure. Together with a detailed analysis of lithium-ion dynamics, these results provide new insights into how structural coherence and disorder govern both transport and vibrational properties in fast ionic conductors. |
| 536 | _ | _ | |a 1221 - Fundamentals and Materials (POF4-122) |0 G:(DE-HGF)POF4-1221 |c POF4-122 |f POF IV |x 0 |
| 588 | _ | _ | |a Dataset connected to CrossRef, Journals: juser.fz-juelich.de |
| 700 | 1 | _ | |a Strotmann, Kyra |0 P:(DE-HGF)0 |b 1 |
| 700 | 1 | _ | |a Faka, Vasiliki |0 P:(DE-HGF)0 |b 2 |
| 700 | 1 | _ | |a Maus, Oliver |0 P:(DE-HGF)0 |b 3 |
| 700 | 1 | _ | |a Abernathy, Douglas L. |0 P:(DE-HGF)0 |b 4 |
| 700 | 1 | _ | |a Granroth, Garrett E. |0 P:(DE-HGF)0 |b 5 |
| 700 | 1 | _ | |a Jalarvo, Niina H. |0 P:(DE-Juel1)143752 |b 6 |
| 700 | 1 | _ | |a Li, Cheng |0 P:(DE-Juel1)172659 |b 7 |
| 700 | 1 | _ | |a Suard, Emmanuelle |0 P:(DE-HGF)0 |b 8 |
| 700 | 1 | _ | |a Zeier, Wolfgang |0 P:(DE-Juel1)184735 |b 9 |e Corresponding author |
| 773 | _ | _ | |a 10.1039/D5TA07185B |g p. 10.1039.D5TA07185B |0 PERI:(DE-600)2702232-8 |p 39211-39228 |t Journal of materials chemistry / A |v 13 |y 2025 |x 2050-7488 |
| 856 | 4 | _ | |y OpenAccess |u https://juser.fz-juelich.de/record/1047538/files/d5ta07185b.pdf |
| 856 | 4 | _ | |y OpenAccess |u https://juser.fz-juelich.de/record/1047538/files/revised_manuscript.pdf |
| 909 | C | O | |o oai:juser.fz-juelich.de:1047538 |p openaire |p open_access |p VDB |p driver |p dnbdelivery |
| 910 | 1 | _ | |a Forschungszentrum Jülich |0 I:(DE-588b)5008462-8 |k FZJ |b 9 |6 P:(DE-Juel1)184735 |
| 913 | 1 | _ | |a DE-HGF |b Forschungsbereich Energie |l Materialien und Technologien für die Energiewende (MTET) |1 G:(DE-HGF)POF4-120 |0 G:(DE-HGF)POF4-122 |3 G:(DE-HGF)POF4 |2 G:(DE-HGF)POF4-100 |4 G:(DE-HGF)POF |v Elektrochemische Energiespeicherung |9 G:(DE-HGF)POF4-1221 |x 0 |
| 914 | 1 | _ | |y 2025 |
| 915 | _ | _ | |a Creative Commons Attribution CC BY 3.0 |0 LIC:(DE-HGF)CCBY3 |2 HGFVOC |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0200 |2 StatID |b SCOPUS |d 2024-12-05 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0160 |2 StatID |b Essential Science Indicators |d 2024-12-05 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)1160 |2 StatID |b Current Contents - Engineering, Computing and Technology |d 2024-12-05 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)1150 |2 StatID |b Current Contents - Physical, Chemical and Earth Sciences |d 2024-12-05 |
| 915 | _ | _ | |a WoS |0 StatID:(DE-HGF)0113 |2 StatID |b Science Citation Index Expanded |d 2024-12-05 |
| 915 | _ | _ | |a IF >= 10 |0 StatID:(DE-HGF)9910 |2 StatID |b J MATER CHEM A : 2022 |d 2024-12-05 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0150 |2 StatID |b Web of Science Core Collection |d 2024-12-05 |
| 915 | _ | _ | |a OpenAccess |0 StatID:(DE-HGF)0510 |2 StatID |
| 915 | _ | _ | |a JCR |0 StatID:(DE-HGF)0100 |2 StatID |b J MATER CHEM A : 2022 |d 2024-12-05 |
| 915 | _ | _ | |a National-Konsortium |0 StatID:(DE-HGF)0430 |2 StatID |d 2024-12-05 |w ger |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0300 |2 StatID |b Medline |d 2024-12-05 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0199 |2 StatID |b Clarivate Analytics Master Journal List |d 2024-12-05 |
| 920 | _ | _ | |l yes |
| 920 | 1 | _ | |0 I:(DE-Juel1)IMD-4-20141217 |k IMD-4 |l Helmholtz-Institut Münster Ionenleiter für Energiespeicher |x 0 |
| 980 | _ | _ | |a journal |
| 980 | _ | _ | |a VDB |
| 980 | _ | _ | |a UNRESTRICTED |
| 980 | _ | _ | |a I:(DE-Juel1)IMD-4-20141217 |
| 980 | 1 | _ | |a FullTexts |
| Library | Collection | CLSMajor | CLSMinor | Language | Author |
|---|