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@INPROCEEDINGS{Heinze:1048340,
author = {Heinze, Leonie},
title = {{Q}uantum criticality and dimensional reduction in the
sawtooth chain material atacamite},
reportid = {FZJ-2025-04562},
year = {2025},
abstract = {Quantum magnets with geometrical frustration stand out due
to their highly degenerate ground states and their
susceptibility to be tuned by applying pressure or magnetic
field. Such tuning can lead to quantum phase transitions
from ordered to disordered states, or vice versa, with the
emergent quantum critical points (QCPs) determining the
deformed entropy landscapes in the respective phase
diagrams. While, in general, there is fundamental interest
in using the properties arising from such distorted entropy
landscapes for applications (e.g. the magnetocaloric effect
for low-temperature cooling), I address here the role of
residual exchange interactions in real materials. I
demonstrate that a QCP can develop on a lower energy scale
measured against the leading exchange couplings in the
system. In this talk, I present the case of the mineral
atacamite Cu$_2$Cl(OH)$_3$, a sawtooth-chain compound where
the non-uniform antiferromagnetic chain units [J ~ 336 K
(basal-basal), J' ~ 102 K (basal-apical)] are embedded into
a weak 3D network of interchain couplings. I will show that
the magnetic phase diagram of atacamite contains a
field-induced quantum critical point at 21.9(1) T (H || c
axis) which emerges on a much lower energy scale compared to
the leading terms in the spin Hamiltonian derived by means
of density-functional theory. The QCP separates field
regions with and without long-range magnetic order. In the
latter, underpinned by numerical results, the sawtooth
chains decompose, but far away from full field
polarization.},
month = {Oct},
date = {2025-10-07},
organization = {JCNS Workshop 2025: Trends and
Perspectives in Neutron Scattering.
Quantum Materials: Theory and
Experiments, Tutzing (Germany), 7 Oct
2025 - 9 Oct 2025},
subtyp = {Invited},
cin = {JCNS-4 / JCNS-3 / MLZ / JCNS-FRM-II},
cid = {I:(DE-Juel1)JCNS-4-20201012 / I:(DE-Juel1)JCNS-3-20170926 /
I:(DE-588b)4597118-3 / I:(DE-Juel1)JCNS-FRM-II-20110218},
pnm = {6G4 - Jülich Centre for Neutron Research (JCNS) (FZJ)
(POF4-6G4) / 632 - Materials – Quantum, Complex and
Functional Materials (POF4-632)},
pid = {G:(DE-HGF)POF4-6G4 / G:(DE-HGF)POF4-632},
experiment = {EXP:(DE-MLZ)External-20140101},
typ = {PUB:(DE-HGF)6},
url = {https://juser.fz-juelich.de/record/1048340},
}