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@INPROCEEDINGS{Heinze:1048341,
author = {Heinze, Leonie and Kastner, C. and Jeschke, H. O. and
Reehuis, M. and Beauvois, K. and Ouladdiaf, B. and
Yokaichiya, F. and Bert, F. and Hicken, T. J. and Krieger,
J. A. and Luetkens, H. and Allen, J. L. and Feyerherm, R.
and Menzel, D. and Wolter, A. U. B. and Rule, K. C. and
Litterst, F. J. and Rößler, U. K. and Süllow, S.},
title = {{M}agnetism of the distorted kagome material clinoatacamite
{C}u$_2${C}l({OH})$_3$},
reportid = {FZJ-2025-04563},
year = {2025},
abstract = {Structurally, the mineral clinoatacamite Cu$_2$Cl(OH)$_3$
is closely related to the kagome material herbertsmithite
Zn$_3$CuCl$_2$(OH)$_6$. In clinoatacamite, however, the
kagome motif of Cu sites is embedded into a low-symmetry
crystal structure, which causes a distortion of the kagome
plane as well as different site symmetries for the kagome Cu
sites. Unlike the quantum spin liquid candidate
herbertsmithite, clinoatacamite undergoes a magnetic
transition at 18.1 K. Its magnetic ground states have
remained inconclusive to date. Here, we will revisit the
magnetic properties using single-crystalline material. We
will first demonstrate using density-functional theory that
the dominant magnetic exchange couplings in this material
form non-uniform antiferromagnetic kagome layers of Cu sites
with weak ferromagnetic couplings to the interlayer Cu site.
Further, we have characterized clinoatacamite by means of
thermodynamic measurement techniques, muon spin
rotation/relaxation as well as neutron diffraction. We
reveal a zero-field magnetic phase diagram which is far more
complex than previously anticipated. We discuss our data
within a scenario of competing order parameters on the
inequivalent Cu sites.},
month = {Oct},
date = {2025-10-27},
organization = {Munich Quantum Matter Days, Munich
(Germany), 27 Oct 2025 - 31 Oct 2025},
subtyp = {After Call},
cin = {JCNS-4 / JCNS-3 / MLZ / JCNS-FRM-II},
cid = {I:(DE-Juel1)JCNS-4-20201012 / I:(DE-Juel1)JCNS-3-20170926 /
I:(DE-588b)4597118-3 / I:(DE-Juel1)JCNS-FRM-II-20110218},
pnm = {6G4 - Jülich Centre for Neutron Research (JCNS) (FZJ)
(POF4-6G4) / 632 - Materials – Quantum, Complex and
Functional Materials (POF4-632)},
pid = {G:(DE-HGF)POF4-6G4 / G:(DE-HGF)POF4-632},
experiment = {EXP:(DE-MLZ)External-20140101},
typ = {PUB:(DE-HGF)24},
url = {https://juser.fz-juelich.de/record/1048341},
}