001048736 001__ 1048736 001048736 005__ 20260108204821.0 001048736 037__ $$aFZJ-2025-04851 001048736 041__ $$aEnglish 001048736 1001_ $$0P:(DE-Juel1)192222$$aJindamol, Hathairut$$b0$$eCorresponding author 001048736 1112_ $$aSEB Annual Conference Antwerp 2025$$cAntwerp$$d2025-07-08 - 2025-07-11$$gSEB$$wBelgium 001048736 245__ $$aAdvanced mathematical modelling of hyperspectral data to quantify the optically inactive secondary metabolites eugenol and methyl eugenol in the medicinal plant holy basil 001048736 260__ $$c2025 001048736 3367_ $$033$$2EndNote$$aConference Paper 001048736 3367_ $$2DataCite$$aOther 001048736 3367_ $$2BibTeX$$aINPROCEEDINGS 001048736 3367_ $$2DRIVER$$aconferenceObject 001048736 3367_ $$2ORCID$$aLECTURE_SPEECH 001048736 3367_ $$0PUB:(DE-HGF)6$$2PUB:(DE-HGF)$$aConference Presentation$$bconf$$mconf$$s1767868779_2522$$xAfter Call 001048736 520__ $$aThe quantification of secondary metabolite content is crucial for the industrial production of high-quality essential oil from medicinal plants, i.e. to determine an optimal harvest time to achieve the desired quality. Spectral reflectance measurements provide a potential technique to perform non-destructive and real-time monitoring of secondary metabolite content. However, not all secondary metabolites are optically active in the range of hyperspectral sensors. In this study, a method for the non-destructive quantification of eugenol (Eu) and methyl eugenol (MeEu) in holy basil (Ocimum tenuiflorum L.) was developed by combining leaf-level hyperspectral measurements with mathematical modelling based on partial least squares regression (PLSR). To generate a wide range dataset of secondary metabolite content, three experiments investigating developmental variation, osmotic stress response and secondary metabolism induction by methyl jasmonate were conducted with two commercial cultivars. Hyperspectral point measurement (350-2500 nm) of individual leaves were combined with destructive quantification of Eu and MeEu by gas chromatography-mass spectrometry. We observed variation of Eu and MeEu concentrations between cultivars, treatments, and leaf ages. PLSR modelling based on the full wavelength spectrum resulted in quantification of Eu and MeEu with R2 of 0.62 and 0.70, respectively, with RMSEP of 1.10 and 0.98. We explain the high correlation by an indirect quantification of these compounds based on associated changes in plant secondary metabolism. This study demonstrated that hyperspectral data combined with PLSR provides a promising technique for the non-destructive quantification of foliar secondary metabolites for industrial applications even in absence of specific absorption feature within the measurement range. 001048736 536__ $$0G:(DE-HGF)POF4-2171$$a2171 - Biological and environmental resources for sustainable use (POF4-217)$$cPOF4-217$$fPOF IV$$x0 001048736 7001_ $$0P:(DE-Juel1)129410$$aThiele, Björn$$b1 001048736 7001_ $$0P:(DE-HGF)0$$aWuyts, Nathalie$$b2 001048736 7001_ $$0P:(DE-Juel1)142555$$aMüller-Linow, Mark$$b3 001048736 7001_ $$0P:(DE-HGF)0$$aChutimaukul, Panita$$b4 001048736 7001_ $$0P:(DE-HGF)0$$aMosaleeyanon, Kriengkrai$$b5 001048736 7001_ $$0P:(DE-HGF)0$$aToojinda, Theerayut$$b6 001048736 7001_ $$0P:(DE-Juel1)129388$$aRascher, Uwe$$b7 001048736 7001_ $$0P:(DE-Juel1)168454$$aJunker-Frohn, Laura$$b8 001048736 909CO $$ooai:juser.fz-juelich.de:1048736$$pVDB 001048736 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)192222$$aForschungszentrum Jülich$$b0$$kFZJ 001048736 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)129410$$aForschungszentrum Jülich$$b1$$kFZJ 001048736 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)142555$$aForschungszentrum Jülich$$b3$$kFZJ 001048736 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)129388$$aForschungszentrum Jülich$$b7$$kFZJ 001048736 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)168454$$aForschungszentrum Jülich$$b8$$kFZJ 001048736 9131_ $$0G:(DE-HGF)POF4-217$$1G:(DE-HGF)POF4-210$$2G:(DE-HGF)POF4-200$$3G:(DE-HGF)POF4$$4G:(DE-HGF)POF$$9G:(DE-HGF)POF4-2171$$aDE-HGF$$bForschungsbereich Erde und Umwelt$$lErde im Wandel – Unsere Zukunft nachhaltig gestalten$$vFür eine nachhaltige Bio-Ökonomie – von Ressourcen zu Produkten$$x0 001048736 920__ $$lyes 001048736 9201_ $$0I:(DE-Juel1)IBG-2-20101118$$kIBG-2$$lPflanzenwissenschaften$$x0 001048736 980__ $$aconf 001048736 980__ $$aVDB 001048736 980__ $$aI:(DE-Juel1)IBG-2-20101118 001048736 980__ $$aUNRESTRICTED