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@INPROCEEDINGS{Rameker:1048905,
author = {Rameker, Robert and Poc, J.-P. and Jovanovic, S. and Oeß,
C. and Liu, Jialiang and Speer, S. and Fröhlich, K. and
Daniel, D. T. and Park, J. and Basak, S. and Karl, A. and
Jodat, E. and Eichel, R.-A. and Granwehr, J.},
title = {{A} novel perspective on “{F}enton-like” degradation
studies on proton exchange membranes},
school = {RWTH Aachen},
reportid = {FZJ-2025-05006},
year = {2025},
abstract = {Understanding membrane degradation under realistic
conditions is critical to improve the lifetime and
commercial viability of PEM electrolyzers. This study
re-evaluates conventional ex-situ Fenton degradation tests,
which simulate long-term radical-driven membrane damage
using high concentrations of Fe²⁺ and H₂O₂. This
study focuses on evaluating their relevance to in-operando
degradation mechanisms and to gain an in-depth understanding
of morphological and chemical degradation processes. By
combining microscopic, spectroscopic, and electrochemical
analyses, it is observed that morphological damage from
oxygen evolution, rather than radical-induced chain
scission, dominates under “Fenton-like” AST conditions.
This challenges current AST design and motivates revised
protocols aligned with true PEM electrolyzer operation.},
month = {Jul},
date = {2025-07-02},
organization = {H2giga Abschlusskonferenz, Frankfurt
(Germany), 2 Jul 2025 - 3 Jul 2025},
subtyp = {Other},
cin = {IET-1},
cid = {I:(DE-Juel1)IET-1-20110218},
pnm = {1231 - Electrochemistry for Hydrogen (POF4-123) / HITEC -
Helmholtz Interdisciplinary Doctoral Training in Energy and
Climate Research (HITEC) (HITEC-20170406)},
pid = {G:(DE-HGF)POF4-1231 / G:(DE-Juel1)HITEC-20170406},
typ = {PUB:(DE-HGF)24},
url = {https://juser.fz-juelich.de/record/1048905},
}