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@MASTERSTHESIS{AkueGoeh:1049792,
author = {Akue-Goeh, Adole Imelda},
title = {{DEVELOPMENT} {OF} {ACCESSIBLE} {AUTOMATED}
{QUANTIFICATION} {METHODS} {ON} {FIB}/{SEM} {TOMOGRAPHY}
{FOR} {INVESTIGATING} {SOLID} {OXIDE} {ELECTROLYZER} {CELL}
({SOEC}) {AND} {PROTON} {EXCHANGE} {MEMBRANE} {WATER}
{ELECTROLYZER} ({PEMWE}) {DEGRADATION}},
school = {Félix-Houphouët-Boigny of Abidjan (CôTE D'IVOIRE)},
type = {Masterarbeit},
reportid = {FZJ-2025-05576},
pages = {61p},
year = {2025},
note = {Masterarbeit, Félix-Houphouët-Boigny of Abidjan (CôTE
D'IVOIRE), 2025},
abstract = {The expanding hydrogen economy relies on efficient and
durable electrochemical devices, such as Solid Oxide
Electrolysis Cells (SOECs) and Proton Exchange Membrane
Water Electrolyzers (PEMWEs). The performance and lifetime
of these devices are closely linked to their microstructural
properties. Despite the development of advanced
microstructural characterization techniques, like Focused
Ion Beam-Scanning Electron Microscopy (FIB-SEM) for
quantitative analysis, data processing remains challenging
due to the complexity of the data, the large volume
generated and the limited access to advanced computational
tools. This study proposes an automated, modular pipeline
that combines traditional image processing and Random
Forest-based supervised learning to segment the
electrode-catalyst part composed of four layers in SOECs
(Layer 1 to Layer 4 ) and to quantitatively evaluate key
microstructural parameters such as porosity and thickness.
The pipeline is intentionally designed to require minimal
computational resources and remain accessible even to
non-expert users.The training on a representative annotated
dataset of FIB-SEM images (10 training images out of a total
of 200) achieved a layer segmentation accuracy of $68\%$ on
the test dataset. Even though this indicates the need for
additional improvement, it was enough to identify meaningful
structural variations. The utilization of the pipeline
across multiple experimental FIB-SEM datasets enables the
extraction of statistically consistent trends in porosity
and thickness under different operational conditions:
pristine, 100-hour and 200-hour run cells. layer 4 exhibits
a distinct rise in porosity, whereas layer 2 displayed a
noticeable change in thickness. These findings show that a
lightweight machine learning approach combined with
traditional image processing can provide meaningful insights
into microstructural parameters. it also emphasizes the
potential for developing a user-friendly and automated
pipeline to assess the complex FIB-SEM datasets of these
electrochemical devices quantitatively in a record time.
Potential enhancement could look closer to the annotation
protocol, feature engineering and combined machine learning
approaches. Keywords: FIB-SEM, microstructural analysis,
Random Forest, image processing, electrolysis.},
cin = {IET-1},
cid = {I:(DE-Juel1)IET-1-20110218},
pnm = {1231 - Electrochemistry for Hydrogen (POF4-123)},
pid = {G:(DE-HGF)POF4-1231},
typ = {PUB:(DE-HGF)19},
url = {https://juser.fz-juelich.de/record/1049792},
}