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@ARTICLE{Eicheldinger:1050295,
author = {Eicheldinger, Markus and Miranda Laferte, Erick and
Castilla, Francisco and Jordan, Nadine and
Santiago-Schübel, Beatrix and Hidalgo, Patricia},
title = {{C}rotoxin {B} from the {S}outh {A}merican rattlesnake
{C}rotalus vegrandisblocks voltage-gated calcium channels
independent of its intrinsiccatalytic activity},
journal = {Toxins},
volume = {18},
number = {1},
issn = {2072-6651},
address = {Basel},
publisher = {MDPI},
reportid = {FZJ-2026-00105},
pages = {18010036},
year = {2026},
abstract = {Neurotoxicity following South American Crotalus rattlesnake
bite is primarily caused by crotoxin, the most abundant
component in their venom. Despite the central role of
voltage-gated calcium channels (CaV) in neurotransmission,
direct targetability by crotoxin has been poorly explored.
Crotoxin is a non-covalent heterodimer formed by an acidic
subunit (CA) and a basic toxic phospholipase A2 subunit
(CB). Here, we chromatographically isolated the CB subunit
from Crotalus vegrandis and studied its effect on CaV
heterologously expressed in tsA201 cells using the
whole-cell patch-clamp technique. Mass spectrometry analysis
identified a protein that matched with $97\%$ sequence
coverage the CBc isoform from Crotalus durissus terrificus.
Isolated CB exhibited moderate phospholipase activity that
was not correlated to its cytotoxic effect on cultured
tsA201 cells. Using Ba2+ as a charge carrier to prevent the
enzymatic activity, we found that CB inhibited currents
mediated by the N-type CaV2.2 and CaV1.2 L-type calcium
channels, in a dose–dependent manner, with higher potency
for the latter, and negligible changes in the voltage
dependence of channel activation. Our results reveal a novel
phospholipase-independent biological activity and a
molecular target of CB providing new insights into the
pathophysiology of Crotalus snakebite envenoming with
potential clinical therapeutic implications.},
cin = {IBI-1},
ddc = {610},
cid = {I:(DE-Juel1)IBI-1-20200312},
pnm = {5243 - Information Processing in Distributed Systems
(POF4-524)},
pid = {G:(DE-HGF)POF4-5243},
typ = {PUB:(DE-HGF)16},
doi = {10.3390/toxins18010036},
url = {https://juser.fz-juelich.de/record/1050295},
}